The combination of attractive supramolecular interactions of a hydrophobic Au-metallopeptide with the shielding effect of flexible oligoethylene glycol chains provides access to a stepwise self-assembly of a Au-metalloamphiphile in water. Kinetic control of the supramolecular polymer morphology is achieved using a temperature-dependent assembly protocol, which yields low dispersity supramolecular polymers (metastable state I) or helical bundled nanorods (state II).
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jacs.7b08189 | DOI Listing |
Publication Analysis
Top Keywords
stepwise self-assembly
8
kinetically controlled
4
controlled stepwise
4
self-assembly au-metallopeptides
4
au-metallopeptides water
4
water combination
4
combination attractive
4
attractive supramolecular
4
supramolecular interactions
4
interactions hydrophobic
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!