In the title compound, [Cu(CHNO)(CHN)(HO)]·2HO, the Cu atom is coordinated by three O atoms and two N atoms, provided by a tridentate pyridine-2,6-di-carboxyl-ate (pdc), one pyrazole and one water ligand, forming a slightly distorted square-pyramidal geometry [range of O-Cu-O and O-Cu-N bond angles = 79.55 (8)-166.22 (10)°]. The water mol-ecule is positioned at the apical position. In the crystal, the complex mol-ecule and the two crystallographically independent non-coordinating water mol-ecules are linked into a supra-molecular layer structure parallel to the plane O-H⋯O and N-H⋯O hydrogen bonds.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730243 | PMC |
http://dx.doi.org/10.1107/S2056989017016231 | DOI Listing |
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