The local functionalities of biocompatible objects can be characterized under conditions similar to the operating ones, using scanning electrochemical microscopy (SECM). In the case of alginate beads entrapping carbon nanotubes (CNTs), SECM allows evidencing of the local conductivity, organization, and communication between the CNTs. It shows that the CNT network is active enough to allow long range charge evacuation, enabling the use of alginate/CNT beads as soft 3D electrodes. Direct connection or local interrogation by a microelectrode allows visualization of their communication as a network and eventually the study of them individually at the nanoscale.
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http://dx.doi.org/10.1039/c5sc00549c | DOI Listing |
J Phys Chem B
November 2024
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
The chemistry of molten salts has attracted great research interest owing to their wide applications in diverse fields. In the pyrochemical reprocessing of spent nuclear fuel or molten salt nuclear reactors, lanthanide elements as the principal fission products bring about changes in the composition and properties of molten salts. Herein, we report a comprehensive study on the coordination chemistry of the representative trivalent lanthanide ions (La/Nd) in LiCl-KCl-CsCl using a multiscale strategy combining Raman spectroscopy, deep learning, and large-scale molecular dynamics (MD) simulations.
View Article and Find Full Text PDFChemSusChem
October 2024
Catalonia Institute for Energy Research-IREC, Jardins de les Dones de Negre 1, 2ª pl., Sant Adrià de Besòs, Catalonia, 08930, Spain.
The electrochemical glucose oxidation reaction (GOR) presents an opportunity to produce hydrogen and high-value chemical products. Herein, we investigate the effect of Sn in Ni nanoparticles for the GOR to formic acid (FA). Electrochemical results show that the maximum activity is related to the amount of Ni, as Ni sites are responsible for catalyzing the GOR via the NiOOH/Ni(OH) pair.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
October 2024
Aix Marseille University, CNRS, BIP - UMR 7281, IMM - FR3479, 13402 Marseille, France.
Copper homeostasis mechanisms are critical for bacterial resistance to copper-induced stress. The multicopper oxidase copper efflux oxidase (CueO) is part of the copper detoxification system in aerobic conditions. CueO contains a methionine-rich (Met-rich) domain believed to interact with copper, but its exact function and the importance of related copper-binding sites remain unclear.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, United States.
Hierarchical superstructures, ubiquitously found in nature, offer enhanced efficiency in both substance reaction and mass transport owing to their unique multiscale features. Inspired by these natural systems, this research reports a general and scalable electrochemical scheme for creating highly branched, multilevel porous superstructures on various electrically conductive substrates. These structures exhibit cascading features from centimeters, submillimeters, micrometers, down to sub-100 nm, significantly increasing the surface area of substrates, such as foams, foils, and carbon cloth by 2 orders of magnitude─among the highest reported enhancements.
View Article and Find Full Text PDFPolymers (Basel)
August 2024
Department of Preventive, Community Dentistry and Oral Health, Center for Advanced Technologies in Dental Prosthodontics, Faculty of Dental Medicine, "Victor Babeș" University of Medicine and Pharmacy Timișoara, Eftimie Murgu Sq. No. 2, 300041 Timișoara, Romania.
(1) Background: The adhesion and microbiological behaviour of thermoplastic PETG dental appliance surfaces is governed by roughness parameters. The aim of this research was to evaluate the antibiofilm activity of alkaline peroxide-based disinfectant in Candida albicans biofilms on thermoplastic PETG, related to artificial ageing and surface characteristics, on multiscale levels. (2) Methods: In the present study, two PETG materials were investigated: Crystal (Bio Art Dental Equipment, Sao Carlos, Brazil), noted as C, and Duran (Scheu-Dental GmbH, Iserlohn, Germany)-noted as D.
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