AI Article Synopsis
- The report discusses using LC-MS/MS to separate and analyze dodecanol and ethoxylated fatty alcohols.
- The substances were derivatized with phenyl isocyanate and separated using a C18 column, employing a specific solvent mixture.
- The method demonstrated high sensitivity with low detection and quantification limits and was applied to analyze environmental samples from the Warta River in Poznan.
Article Abstract
Abstract: This report describes the application of LC-MS/MS for the separation of dodecanol (COH) and homogenous fatty alcohols ethoxylated (AE) containing a dodecyl moiety and 1-9 ethoxy groups. These ethoxylates and free alcohol were derivatized for LC-MS/MS analysis with phenyl isocyanate (PIC). The derivatives of analytes with PIC were separated using a C18 column. Gradient elution with a mixture of ethyl acetate and acetonitrile (5 mM) was employed. The described determination method is characterized by low detection limits (range from 0.005 µg L for: COH, CEO to 1 µg L for CEO) and quantification limits (range from 0.01 µg L for: CEO to 2 µg L for CEO). The developed and validated method was used in combination with liquid-liquid extraction (using ethyl acetate) in order to identify and quantitatively determine the COH and CEO present in environmental samples collected from Warta river water in Poznan.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5686276 | PMC |
| http://dx.doi.org/10.1007/s11743-017-2015-z | DOI Listing |
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