A Li-Air Battery with Ultralong Cycle Life in Ambient Air.

Adv Mater

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science and Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.

Published: January 2018

AI Article Synopsis

  • Li-air batteries are a strong candidate for future electronics due to their high energy density but struggle with cyclability in ambient air.
  • Researchers developed Li-air batteries that can achieve 610 cycles by using low-density polyethylene film to prevent water erosion and a gel electrolyte with LiI, which enhances performance.
  • The design allows for flexibility, making these batteries ideal for use in portable and wearable devices.

Article Abstract

The Li-air battery represents a promising power candidate for future electronics due to its extremely high energy density. However, the use of Li-air batteries is largely limited by their poor cyclability in ambient air. Herein, Li-air batteries with ultralong 610 cycles in ambient air are created by combination of low-density polyethylene film that prevents water erosion and gel electrolyte that contains a redox mediator of LiI. The low-density polyethylene film can restrain the side reactions of the discharge product of Li O to Li CO in ambient air, while the LiI can facilitate the electrochemical decomposition of Li O during charging, which improves the reversibility of the Li-air battery. All the components of the Li-air battery are flexible, which is particularly desirable for portable and wearable electronic devices.

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Source
http://dx.doi.org/10.1002/adma.201704378DOI Listing

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