Brass and Bronze as Effective CO Reduction Electrocatalysts.

Angew Chem Int Ed Engl

Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T1Z1, Canada.

Published: December 2017

Electrochemically reducing CO into fuels using renewable electricity is a contemporary global challenge that requires significant advances in catalyst design. Photodeposition techniques were used to screen ternary alloys of Cu-Zn-Sn, which includes brass and bronze, for the electrocatalytic reduction of CO to CO and formate. This analysis identified Cu Zn Sn and Cu Sn to be capable of reaching Faradaic efficiencies of >80 % for CO and formate formation, respectively, and capable of achieving partial current densities of 3 mA cm at an overpotential of merely 200 mV.

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http://dx.doi.org/10.1002/anie.201709932DOI Listing

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