Transparent conducting films (TCFs) are critical components of many optoelectronic devices that pervade modern technology. Due to their excellent optoelectronic properties and flexibility, single-walled carbon nanotube (SWNT) films are regarded as an important alternative to doped metal oxides or brittle and expensive ceramic materials. Compared with liquid-phase processing, the dry floating catalyst chemical vapor deposition (FCCVD) method without dispersion of carbon nanotubes (CNTs) in solution is more direct and simpler. By overcoming the tradeoff between CNT length and solubility during film fabrication, the dry FCCVD method enables production of films that contain longer CNTs and offer excellent optoelectronic properties. This review focuses on fabrication of SWNT films using the dry FCCVD method, covering SWNT synthesis, thin-film fabrication and performance regulation, the morphology of SWNTs and bundles, transparency and conductivity characteristics, random bundle films, patterned films, individual CNT networks, and various applications, especially as TCFs in touch displays. Films based on SWNTs produced by the dry FCCVD method are already commercially available for application in touch display devices. Further research on the dry FCCVD method could advance development of not only industrial applications of CNTs but also the fundamental science of related nanostructured materials and nanodevices.
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http://dx.doi.org/10.1007/s41061-017-0178-8 | DOI Listing |
Adv Mater
January 2025
Department of Nano Engineering, Department of Nano Science and Technology, Sungkyunkwan University Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University (SKKU), Seobu-ro 2066, Jangan-gu, Suwon, 16419, Republic of Korea.
Carbon nanotubes (CNTs) produced by the floating-catalyst chemical vapor deposition (FCCVD) method are among the most promising nanomaterials of today, attracting interest from both academic and industrial sectors. These CNTs exhibit exceptional electrical conductivity, optical properties, and mechanical resilience due to their binder-free and low-defect structure, while the FCCVD method enables their continuous and scalable synthesis. Among the methodological FCCVD variations, aerosol CVD' is distinguished by its production of freestanding thin films comprising macroscale CNT networks, which exhibit superior performance and practical applicability.
View Article and Find Full Text PDFLangmuir
October 2024
Department of Engineering, University of Cambridge, Cambridge CB2 1PZ, United Kingdom.
In floating catalyst chemical vapor deposition (FCCVD), high-aspect-ratio carbon nanotubes (CNTs) are produced in the gas phase at high number concentrations and undergo collision and agglomeration, eventually giving rise to a macroscale aerogel, enabling functional material forms such as fibers or mats to be obtained directly from the synthesis process. The self-assembly behavior between high-aspect-ratio CNTs dictates the resulting morphology at the nanoscale and subsequently the bulk properties of the CNT product. Reorientation between CNTs after collision is a critical step that results in bundle formation and precedes aerogel formation.
View Article and Find Full Text PDFNanomaterials (Basel)
June 2024
Department of Physics, Florida International University, Miami, FL 33199, USA.
Single-walled carbon nanotube (SWCNT) thin films were synthesized by using a floating catalyst chemical vapor deposition (FCCVD) method with a low flow rate (200 sccm) of mixed gases (Ar and H). SWCNT thin films with different thicknesses can be prepared by controlling the collection time of the SWCNTs on membrane filters. Transmission electron microscopy (TEM) showed that the SWCNTs formed bundles and that they had an average diameter of 1.
View Article and Find Full Text PDFJ Am Chem Soc
April 2024
Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
With impressive individual properties, carbon nanotubes (CNTs) show great potential in constructing high-performance fibers. However, the tensile strength of as-prepared carbon nanotube fibers (CNTFs) by floating catalyst chemical vapor deposition (FCCVD) is plagued by the weak intertube interaction between the essential CNTs. Here, we developed a chlorine (Cl)/water (HO)-assisted length furtherance FCCVD (CALF-FCCVD) method to modulate the intertube interaction of CNTs and enhance the mechanical strength of macroscopic fibers.
View Article and Find Full Text PDFSci Rep
March 2024
Graduate School of Pure and Applied Science, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba, Ibaraki, 305-8573, Japan.
We performed molecular dynamics simulations of carbon nanotube (CNT) to elucidate the growth process in the floating catalyst chemical vapor deposition method (FCCVD). FCCVD has two features: a nanometer-sized cementite (Fe C) particle whose melting point is depressed because of the larger surface-to-volume ratio and tensile strain between the growing CNT and the catalyst. The simulations, including these effects, demonstrated that the number of 6-membered rings of the (6,4) chiral CNT constantly increased at a speed of at , whereas those of the armchair and zigzag CNTs were stopped in the simulations and only reached half of the numbers for chiral CNT.
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