Multi-core TIPSTAP-constructs of different dimensionality were created via "geometrization" of the monomeric, highly crystalline parent using alkyne linkers. Morphological diversity is produced, while the material acceptor strength remains untouched. We establish structure-function relationships as the bulk morphology is predicted from the molecular geometry.
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NaCl Micro-Crystal as a Molecular Mold for Enhanced Synthesis of Planar Phenazines and Their Applications on Chemosensing and a Full-Color Fluorescent Material.
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State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China.
NaCl has been successfully used as a template for the synthesis of 2D nanomaterials, but it is seldom used for the construction of flat small organic molecules. Herein, a simple, low-cost, and highly efficient synthesis of phenazines with planar main frames, such as 5-phenyl-5,14-dihydro-5,7,12,14-tetraazapentacene, in the presence of NaCl micro-crystal as a kind of molecular mold is described. The reactants were mixed with NaCl powder and heated to 320 °C for 5 min.
View Article and Find Full Text PDFTetraazapentacene constructs: controlling bulk-morphology through molecular dimensionality.
Chem Commun (Camb)
January 2018
Organisch Chemisches Institut, Im Neuenheimer Feld 271, 62912 Heidelberg, Germany.
Multi-core TIPSTAP-constructs of different dimensionality were created via "geometrization" of the monomeric, highly crystalline parent using alkyne linkers. Morphological diversity is produced, while the material acceptor strength remains untouched. We establish structure-function relationships as the bulk morphology is predicted from the molecular geometry.
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