We report the discovery in space of methyl silane, CHSiH, from observations of ten rotational transitions between 80 and 350 GHz ( from 4 to 16) with the IRAM 30 m radio telescope. The molecule was observed in the envelope of the C-star IRC +10216. The observed profiles and our models for the expected emission of methyl silane suggest that the it is formed in the inner zones of the circumstellar envelope, 1-40 , with an abundance of (0.5-1) × 10 relative to H. We also observed several rotational transitions of silyl cyanide (SiHCN), confirming its presence in IRC +10216 in particular, and in space in general. Our models indicate that silyl cyanide is also formed in the inner regions of the envelope, around 20 , with an abundance relative to H of 6×10. The possible formation mechanisms of both species are discussed. We also searched for related chemical species but only upper limits could be obtained.
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http://dx.doi.org/10.1051/0004-6361/201731672 | DOI Listing |
Polymers (Basel)
January 2025
Jožef Stefan Institute, Department of Physical and Organic Chemistry, Jamova c. 39, SI-1000 Ljubljana, Slovenia.
The study aimed to develop a superhydrophobic coating on the aluminium alloy 2024-T3 surface. The desired surface roughness and low surface energy were achieved with SiO nanoparticles, synthesised via the Stöber method and modified with alkyl silane (AS) or perfluoroalkyl silane (FAS). To enhance particle adhesion to the alloy substrate, nanoparticles were incorporated into a hybrid sol-gel coating composed of tetraethyl orthosilicate, methyl methacrylate, and 3-methacryloxypropyl trimethoxysilane.
View Article and Find Full Text PDFMolecules
January 2025
Centre for Surface Chemistry and Catalysis-Characterization and Application Team (COK-KAT), KU Leuven, Celestijnenlaan 200F Box 2461, 3001 Heverlee, Belgium.
This work describes the synthesis of ordered 3D siloxane-silsesquioxane reticular materials with silicate D4R cubes (SiO), harvested from a sacrificial tetrabutylammonium cyclosilicate hydrate (TBA-CySH) precursor, interlinked with octyl and dicyclopentyl (Cp) hydrocarbon functionalities in a one-step synthesis with organodichlorosilanes. Advanced solid-state NMR spectroscopy allowed us to unravel the molecular order of the nodes and their interconnection by the silicone linkers. In the case of octyl-methyl silicone linkers, changing the silane-to-silicate ratio in the synthesis allowed for tuning the length of the linker between the nodes.
View Article and Find Full Text PDFJ Prosthodont Res
January 2025
Department of Comprehensive Dentistry, UT Health San Antonio, San Antonio, USA.
Purpose: To determine the effects of K18 quaternary ammonium methacryloxy silane (QAS) on tissue conditioner materials and their antimicrobial properties.
Methods: 30% K18 QAS in methyl methacrylate (MMA; K18-MMA; 0%, 15%, and 20% w/w) was incorporated into a commercial tissue conditioner (Coe comfort). The degree of curing (Shore A hardness), hydrophilicity (contact angle), flow, liquid sorption, mass loss, and antimicrobial properties of Streptococcus mutans, Streptococcus sanguinis, and Candida albicans were determined.
PLoS One
January 2025
Departamento de Reología y Mecánica de Materiales, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México Ciudad Universitaria, Ciudad de México, México.
A hybrid coating made of poly (methyl methacrylate) with SiO2-TiO2 particles (PMMA/SiO2-TiO2) has been developed for use as a coating on nanosatellites, evaluating its resistance to high vacuum by quantifying its weight loss. The coating was applied on an Al 7075 aluminum substrate used for the aerospace sector. PMMA/SiO2-TiO2 hybrid coatings were prepared using sol-gel reaction in situ assisted with sonochemistry.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan 610065, China. Electronic address:
Xanthan gum (XG), recognized for its environmentally friendly properties and versatile capabilities, has been studied for drilling fluid applications. However, its limited solubility and thermal stability restricts its broader use. In this study, a modified XG derivative, XG-g-KH570 modified SiO, was synthesized by grafting XG with KH570-modified nano-SiO.
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