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Magneto-structural correlation of hexakis-dmso cobalt(ii) complex. | LitMetric

The magnetostructural correlation of the hexakis-dmso cobalt(ii) complex, [Co(dmso)](BPh) (dmso: dimethylsulfoxide), was investigated by single-crystal X-ray diffraction study and magnetic measurements. The magnetic analysis concluded the negative Δ value (H = Δ(L - 2/3) + E(L - L) - (3/2)κλL·S + β[-(3/2)κL + gS]·H (u = x, y, z)), and this was explained by the tetragonal elongation of the octahedral geometry. The magnetostructural correlation was ascertained by both the angular overlap model calculation and the density functional theory calculation.

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http://dx.doi.org/10.1039/c7dt03269bDOI Listing

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