The first example of a stable zincagermylene, :Ge(TBoN)(ZnL*) (TBoN = N(SiMe){B(DipNCH)}, Dip = CHPr-2,6; L* = -N{CH[C(H)Ph]Me-2,6,4}(SiPr)) is prepared and shown to have unprecedented reactivity for a germylene, with respect to the activation of dihydrogen. Computational analyses point towards this being partially derived from the electron releasing nature of the amido-zinc fragment, which leads to a narrowing of the HOMO-LUMO gap in the compound.
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