Facile formation of metallic bismuth/bismuth oxide heterojunction on porous carbon with enhanced photocatalytic activity.

Bismuth/bismuth oxide heterojunction on porous carbon (Bi/BiO@C) was successfully prepared by a surfactant-assisted sol-gel method. This composite photocatalyst was fabricated by depositing BiO and metallic bismuth nanoparticles (NPs) on porous carbon sheets. Bi NPs were created by in-situ reduction of BiO with amorphous carbon. During the synthesis, bismuth and carbon precursors were mixed in different ratios, resulting in distinct amounts of metallic bismuth in the composites. The composites showed large specific surface area and pore volume as well as strong light absorption ability due to the existing carbon. In addition, the plasmonic bismuth NPs were found to behave as a noble metal, which is able to generate hot charge carriers under visible light irradiation. Photocatalytic performance of the Bi/BiO@C composites was investigated by degradation of methylene blue. It turned out that the composites showed much higher efficiency as compared to bare BiO, which may be attributed to the synergistic effects of porous structures, improved optical absorption, and surface plasmon resonance.