A novel effective cellulose-based adsorbent was prepared through two common reactions, which included the esterification of sugarcane bagasse cellulose with excess stearic acid and the reaction of grafting polyacrylamide brush by ultraviolet radiation initiation. The adsorbent can effectively adsorb Hg(II) ion from wastewater. The characterization of the adsorbents was conducted by optical microscope (OM), scanning electron microscopy (SEM-EDS) and infrared spectrometry (FTIR). Full kinetic and thermodynamic investigations as well as isotherm analysis were also undertaken. Due to the abundant amide groups, the cellulose-based adsorbents exhibit excellent adsorption performance for the removal of Hg(II) ion from aqueous solution with a maximum adsorption capacity of 178mg/g. Furthermore, the cellulose-based adsorbents can be easily separated from the aqueous solution after adsorption and regenerated using 0.2M HCl solution, which exhibits high adsorption capacity after six adsorption-desorption cycles. In view of the easily-operated cost-effective preparation technique, substantial adsorption efficiency and excellent adsorption recyclability, therefore, the eco-friendly cellulose-based adsorbents could be used for water purification effectively. More importantly, this work improves value of low-cost biomass resources.
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http://dx.doi.org/10.1016/j.ijbiomac.2017.11.027 | DOI Listing |
Talanta
December 2024
Institute of Atomic and Molecular Physics, Jilin University, Changchun, 130012, China. Electronic address:
Laser-induced breakdown spectroscopy (LIBS) is a rapidly evolving in-situ multi-element analysis technique that has significantly advanced the field of liquid analysis. This study employs a femtosecond laser for quantitative analysis of heavy metals in flowing liquids, exploring its detection sensitivity and accuracy. Femtosecond pulsed laser excitation of water in a dynamic environment generates plasma while effectively preventing liquid splashing.
View Article and Find Full Text PDFTalanta
January 2025
College of Chemistry and Materials Science, Hunan Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, Hengyang Normal University, Hengyang, 421001, China. Electronic address:
The accurate and sensitive quantification of hydroxyl radical (·OH) and glucose is necessary for disease diagnosis and health guidance, but still challenging owing to the low concentration of ·OH and poor water solubility of fluorescent probes. In addition, fluorescent probes may cause secondary pollution to the environment. Here an organic cage was reported as a sensitive fluorescent probe for ·OH and glucose in aqueous solution without serious secondary pollution.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Nano Photocatalysis Lab., Department of Chemistry, College of Science, Shiraz University, Shiraz, 7194684795, I.R. of Iran.
Due to the industry's rapid growth, the presence of organic pollutants, especially antibiotics, in water and wastewater resources is the main concern for wildlife and human health. Therefore, these days, a significant challenge is developing an efficient, sustainable, and eco-friendly photocatalyst. Natural biological models have numerous advantages compared to artificial model materials.
View Article and Find Full Text PDFMol Pharm
January 2025
Department of Pharmaceutical Sciences, College of Pharmacy and Health Sciences, St. John's University, 8000 Utopia Parkway, Queens, New York 11439, United States.
Although glycine is the simplest of the amino acids, its solution and solid-state properties are far from straightforward. The aqueous solubility of glycine plays an important role in various applications, including nutrition, food products, biodegradable plastics, and drug development. There is evidence that glycine in subsaturated pH 3-8 solutions forms a dimer, as suggested by several techniques.
View Article and Find Full Text PDFSci Rep
January 2025
Environment Division, National Institute of Oceanography and Fisheries (NIOF), Kayet Bey, Elanfoushy, Alexandria, Egypt.
In this research, the degradation of Congo red (CR) dye, as an organic pollutant in water, was investigated using microwave-induced reaction technology. This technology requires a microwave-absorbing catalyst and the 2D TiCT MXene was synthesized for that purpose. The synthesized catalyst was characterized using XRD, SEM, TEM, EDX, BET, and XPS techniques.
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