Amplification of a metallacyclic receptor out of a dynamic combinatorial library.

Dalton Trans

Departamento de Química and Centro de Investigacións Científicas Avanzadas (CICA), Facultade de Ciencias, Universidade da Coruña, E-15071 A Coruña, Spain.

Published: November 2017

We present herein the Pt(ii)-directed self-assembly in water of a new conformationally flexible N-monoalkyl-4,4-bipyridinium-based ditopic ligand into a library of six different metallacyclic structures. This constitutionally dynamic library can be pushed to increase the production of one of the supramolecules in aqueous media, either by controlling the concentration of the building blocks or upon addition of an appropriate aromatic substrate.

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Source
http://dx.doi.org/10.1039/c7dt03379fDOI Listing

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