Chiral binary metal-organic frameworks for asymmetric sequential reactions.

Chem Commun (Camb)

School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.

Published: November 2017

Two chiral porous MOFs with precise and appropriate spatial arrangements of different metallosalen active sites are synthesized and used as efficient heterogeneous catalysts for asymmetric sequential alkene epoxidation/epoxide ring-opening reactions with enantioselectivity of up to 99%.

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Source
http://dx.doi.org/10.1039/c7cc06979kDOI Listing

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