A titanocene based metalloligand, Cp*Ti(C2-py), was synthesized and coordinated to either Cu(i) or Pd(ii). The metalloligand binds Cu(i) between its alkynes and Pd(ii) between its pyridinyl rings, acting as a trans-bidentate ligand. In order to bind Pd(ii), significant structural rearrangements were necessary, which required the flexibility of the C-Ti-C hinge on the titanocene metalloligand.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c7dt03252h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A trans-bidentate bis-pyridinyl ligand with a transition metal hinge.
Dalton Trans
November 2017
Department of Chemistry, Furman University, Greenville, SC 29613, USA.
A titanocene based metalloligand, Cp*Ti(C2-py), was synthesized and coordinated to either Cu(i) or Pd(ii). The metalloligand binds Cu(i) between its alkynes and Pd(ii) between its pyridinyl rings, acting as a trans-bidentate ligand. In order to bind Pd(ii), significant structural rearrangements were necessary, which required the flexibility of the C-Ti-C hinge on the titanocene metalloligand.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!