Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)[GeBO(OH)] (1; dima = dimethylamine) and noncentrosymmetric NaGaBO(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped GeBO(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO units and Ga ions and displays weak second-harmonic-generation response.
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| http://dx.doi.org/10.1021/acs.inorgchem.7b02328 | DOI Listing |
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