An iodoplumbate-based organic-inorganic hybrid ferromagnetic semiconductor, [PbCuI(phen)], has been solvothermally synthesized. The ferromagnetic exchange interaction is resulting from the multiple aromatic π-π stacking interactions between the adjacent phen molecules.
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http://dx.doi.org/10.1039/c7dt03237d | DOI Listing |
ACS Appl Mater Interfaces
January 2025
School of Material Science and Engineering, Jiangsu Collaborative Innovation Center for Photovoltaic Science and Engineering, Jiangsu Province Cultivation Base for State Key Laboratory of Photovoltaic Science and Technology, Changzhou University, Changzhou 213164, China.
Lithium (Li) metal's extremely high specific energy and low potential make it critical for high-performance batteries. However, uncontrolled dendrite growth and an unstable solid-electrolyte interphase (SEI) during repeated cycling still seriously hinder its practical application in Li metal batteries. Herein, we demonstrate a facile and effective approach to fabricate a flexible and robust hybrid SEI layer using two kinds of organo-polysulfides with different sulfur chain lengths [bis(3-(triethoxysilyl)propyl)disulfide (Si-O-2S) and bis(3-(triethoxysilyl)propyl)tetrasulfide (Si-O-4S)] as the additives in the electrolyte.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Materials Chemistry Laboratory, Department of Chemistry, School of Natural Sciences, Shiv Nadar Institution of Eminence, Gautam Buddha Nagar, Uttar Pradesh 201314, India.
Cathode materials with both high capacity and high operating voltage are essential for advancing aqueous zinc-ion batteries (ZIBs). Conventional high-capacity materials, such as vanadium-based compounds, typically deliver low discharge voltages. In contrast, organic cathodes show high operating voltages but often exhibit limited capacity.
View Article and Find Full Text PDFNano Lett
January 2025
Key Laboratory of Materials Physics of Ministry of Education, School of Physics, Zhengzhou University, Daxue Road 75, Zhengzhou 450052, China.
Ternary copper halides with an eco-friendly property have emerged as attractive candidates to replace toxic lead-containing perovskites for light-emitting diodes (LEDs), yet achieving long-wavelength electroluminescence remains unexplored. Herein, we report the first realization of orange-emitting LEDs (595 nm) based on nontoxic organic-inorganic PEACuI (PEA = β-phenylethylamine) films enabled by a nonionic surfactant poly(propylene glycol) bis(2-aminopropyl ether) (APPG) chemisorption. Experimental and theoretical analyses rationalize that the APPG additive has strong chemisorption with the Cu-I framework within the grain boundaries of PEACuI films, which not only improves the film's morphology but also passivates the iodine vacancy defects.
View Article and Find Full Text PDFSmall
January 2025
Department of Chemistry, Indian Institute of Technology Indore, Indore, Madhya Pradesh, 453552, India.
Efficient room-temperature sensors for toxic gases are essential to ensure a safe and healthy life. Conducting frameworks have shown great promise in advancing gas sensing technologies. In this study, two new organic-inorganic frameworks [CuX(PPh)(L)], CP1 (X = I) and CP2 (X = Br) have been synthesized using (pyridin-4-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine (L) and triphenylphosphine.
View Article and Find Full Text PDFAdv Mater
January 2025
State Key Laboratory of Organic-Inorganic Composites, State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
The past decades have witnessed the increasing accumulation of plastics, posing a daunting environmental crisis. Among various solutions, converting plastics into value-added products presents a significant endeavor. Here, an electrocatalytic upcycling route that efficiently converts waste poly(butylene terephthalate) plastics into high-value succinic acid with high Faradaic efficiency of 94.
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