Solution-grown films of CsPbBr nanocrystals imbedded in Cs PbBr are incorporated as the recombination layer in light-emitting diode (LED) structures. The kinetics at high carrier density of pure (extended) CsPbBr and the nanoinclusion composite are measured and analyzed, indicating second-order kinetics in extended and mainly first-order kinetics in the confined CsPbBr , respectively. Analysis of absorption strength of this all-perovskite, all-inorganic imbedded nanocrystal composite relative to pure CsPbBr indicates enhanced oscillator strength consistent with earlier published attribution of the sub-nanosecond exciton radiative lifetime in nanoprecipitates of CsPbBr in melt-grown CsBr host crystals and CsPbBr evaporated films.
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http://dx.doi.org/10.1002/adma.201703703 | DOI Listing |
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