The effect of free ammonia (NH or FA), free nitrous acid (HNO or FNA), and total alkalinity (TA) on the performance of a partial nitrification (PN) sequencing batch reactor (SBR) treating anaerobically pretreated pig slurry was studied. The SBR was operated under alternating oxic/anoxic (O/A) conditions and was fed during anoxic phases. This strategy allowed using organic matter to partially remove nitrite (NO) and nitrate (NO) generated during oxic phases. The desired NH to NO ratio of 1.3 g N/g N was obtained when an Ammonium Loading Rate (ALR) of 0.09 g NH-N/L·d was applied. The system was operated at a solid retention time (SRT) of 15-20 d and dissolved oxygen (DO) levels higher than 3 mg O/L during the whole operational period. PN mainly occurred caused by the inhibitory effect of FNA on nitrite oxidizing bacteria (NOB). Once HNO concentration was negligible, NH was fully oxidized to NO in spite of the presence of FA. The use of biomass acclimated to ammonium as inoculum avoided a possible effect of FA on NOB activity.
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http://dx.doi.org/10.1155/2017/6571671 | DOI Listing |
Sci Total Environ
January 2025
School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China.
Ammonia (NH) holds promise as a carbon-free fuel. Blending it with highly reactive fuels could efficiently alleviate issues such as slow burning rates and narrow flammability ranges. Ethanol (CHOH) offers the advantage of carbon neutrality and has a high-octane rating.
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January 2025
Hainan Natural Rubber Technology Innovation Center, Rubber Research Institute, Chinese Academy of Tropical Agricultural Sciences, Haikou 571101, China.
Ammonia is commonly used as a preservative in the production of concentrated natural rubber latex (CNRL) and latex products; however, it poses a serious risk to human health and the environment. In this study, we investigated a thioacetamide derivative (TD) as a preservative of ammonia-free CNRL and the optimization of a stabilization system comprising potassium hydroxide (KOH), lauric acid (LA), and sodium dodecyl sulfate (SDS) to enhance its preservation effect. The results revealed that an optimal amount of TD (0.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Institute of Chemistry Chinese Academy of Sciences, Institute of chemistry, Beiyijie number 2, Zhongguancun, 100190, Beijing, CHINA.
Electrocatalytic nitrate reduction reaction (NO3RR) in alkaline electrolyte presents a sustainable pathway for energy storage and green ammonia (NH3) synthesis. However, it remains challenging to obtain high activity and selectivity due to the limited protonation and/or desorption processes of key intermediates. Herein, we propose a strategy to regulate the acid hardness nature of Cu catalyst by introducing appropriate modifier.
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January 2025
State Key Laboratory of Green Pesticide, Fine Chemical Research and Development Center, Guizhou University, Huaxi District, Guiyang 550025, China.
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January 2025
CBQF-Centro de Biotecnologia e Química Fina, Laboratório Associado, Universidade Católica Portuguesa, Escola Superior de Biotecnologia, Rua Diogo Botelho 1327, 4169-005 Porto, Portugal.
Chronic Kidney Disease (CKD) is a disorder that affects over 10% of the global population, and that would benefit from innovative methodologies that would provide early detection. Since it has been reported that there are high levels of urease in CKD patients' saliva, this sample is a promising non-invasive alternative to blood for CKD detection and monitoring. This work introduces a novel 3D µPAD for quantifying urease activity in saliva in a range of 0.
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