It is very challenging to make materials capable of autonomous oscillation known in many living systems (such as the heartbeat). Herein, we describe an approach to creating a thermo-mechano-thermal feedback loop for thermal phase transition-based polymer actuators, which leads to hour-long, autonomous motion on a substrate surface of constant temperature. We investigated the variables that determine the amplitude and period of the motion, and demonstrated exemplary physical work powered by direct thermomechanical energy conversion. Such continuous motion of a solid polymer driven by thermal energy without the need for temperature up/down switching is unprecedented, and the validated feedback loop can be implemented into other thermal phase transition-based polymer actuators.
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http://dx.doi.org/10.1039/c7sc01792h | DOI Listing |
ACS Omega
January 2025
Ugelstad Laboratory, Department of Chemical Engineering, Norwegian University of Science and Technology (NTNU), 7491 Trondheim, Norway.
Pickering emulsions (PEs) have demonstrated significant potential in various fields, including catalysis, biomedical applications, and food science, with notable advancements in wastewater treatment through photocatalysis. This study explores the development and application of TiO-poly(-isopropylacrylamide) (pNIPAm) composite gels as a novel framework for photocatalytic wastewater remediation. The research focuses on overcoming challenges associated with conventional nanoparticle-based photocatalytic systems, such as agglomeration and inefficient recovery of particles.
View Article and Find Full Text PDFChemistryOpen
January 2025
Department of Chemistry, School of Sciences and Humanities, SR University, Warangal, Telangana, 506371, India.
High-entropy alloys (HEAs), containing five or more elements in equal proportions, have recently made significant achievements in materials science due to their remarkable properties, including high toughness, excellent catalytic, thermal, and electrical conductivity, and resistance to wear and corrosion. This study focuses on a HEA composed of 23Fe-21Cr-18Ni-20Ti-18Mn, synthesized via ball milling. The alloy was treated with hydrochloric acid (HCl) to enhance its active surface area.
View Article and Find Full Text PDFAdv Mater
January 2025
Department of Physics, SUNY University at Buffalo, Buffalo, NY, 14220, USA.
Quasi-2D perovskite made with organic spacers co-crystallized with inorganic cesium lead bromide inorganics is demonstrated for near unity photoluminescence quantum yield at room temperature. However, light emitting diodes made with quasi-2D perovskites rapidly degrade which remains a major bottleneck in this field. In this work, It is shown that the bright emission originates from finely tuned multi-component 2D nano-crystalline phases that are thermodynamically unstable.
View Article and Find Full Text PDFDalton Trans
January 2025
State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), School of Materials Science and Engineering, Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China.
Formamidinium lead triiodide (FAPbI) has received significant attention in the field of perovskite solar cells (PSCs) owing to its excellent optoelectronic properties and high thermal stability. However, the photoactive α-FAPbI perovskites are highly susceptible to degradation into non-perovskite δ-FAPbI phases, especially under humid conditions, which severely diminishes the device performance of FAPbI PSCs. Here, we propose an interfacial seeding strategy for regulating crystallization and stabilizing α-FAPbI perovskites in humid air.
View Article and Find Full Text PDFAdv Mater
January 2025
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Blue phase liquid crystal (BPLC) lasers exhibit exceptional optical quality and tunability to external stimuli, holding significant promise for innovative developments in the field of flexible optoelectronics. However, there remain challenges for BPLC elastomer (BPLCE) lasers in maintaining good optical stability during stretching and varying temperature conditions. In this work, a stretchable laser is developed based on a well-designed BPLCE with a combination of partially and fully crosslinked networks, which can output a single-peak laser under small deformation (44.
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