At the core of the "proton radius puzzle" is a four-standard deviation discrepancy between the proton root-mean-square charge radii () determined from the regular hydrogen (H) and the muonic hydrogen (µp) atoms. Using a cryogenic beam of H atoms, we measured the 2S-4P transition frequency in H, yielding the values of the Rydberg constant = 10973731.568076(96) per meterand = 0.8335(95) femtometer. Our value is 3.3 combined standard deviations smaller than the previous H world data, but in good agreement with the µp value. We motivate an asymmetric fit function, which eliminates line shifts from quantum interference of neighboring atomic resonances.
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http://dx.doi.org/10.1126/science.aah6677 | DOI Listing |
Commun Phys
December 2024
LaserLaB, Department of Physics and Astronomy, Vrije Universiteit Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam, the Netherlands.
Laser spectroscopy of atomic hydrogen and hydrogen-like atoms is a powerful tool for tests of fundamental physics. The 1-2 transition of hydrogen in particular is a cornerstone for stringent Quantum Electrodynamics (QED) tests and for an accurate determination of the Rydberg constant. We report laser excitation of the 1-2 transition in singly-ionized helium (He), a hydrogen-like ion with much higher sensitivity to QED than hydrogen itself.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2024
Department of Chemistry, University of California at Riverside, Riverside, CA 92521, USA.
The ultraviolet (UV) photodissociation dynamics of the 2-buten-2-yl (CH) radical were studied using the high- Rydberg atom time-of-flight (HRTOF) technique in the photolysis region of 226-246 nm. 2-Buten-2-yl radicals were generated by 193 nm photodissociation of the precursor 2-chloro-2-butene. The H-atom photofragment yield (PFY) spectrum of 2-buten-2-yl is broad, peaking at 234 nm.
View Article and Find Full Text PDFJ Mol Model
September 2024
Núcleo de Matemática, Instituto Federal Sudeste de Minas Gerais, Juiz de Fora, MG, Brazil.
Context: Accurate functions to analytically represent the potential energy interactions of CO diatomic system in , , and electronic states are proposed. The new functions depend upon only four parameters directly obtained from experimental data, without any fitting procedure. These functions have been developed from the modified generalized potential proposed by Araújo and Ballester.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2024
Combustion Research Facility, Sandia National Laboratories, Livermore, California 94550, USA.
Dimethyl disulfide (DMDS), one of the smallest organic molecules with an S-S bond, serves as a model system for understanding photofragmentation in polypeptides and proteins. Prior studies of DMDS photodissociation excited at ∼266 nm and ∼248 nm have elucidated the mechanisms of S-S and C-S bond cleavage, which involve the lowest excited electronic states S and S. Far less is known about the dissociation mechanisms and electronic structure of relevant excited states of DMDS excited at ∼200 nm.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2024
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.
Rotationally resolved vibrational spectra of DyO and DyO in a molecular beam are obtained by IR excitation from the X8 ground state and from high- Rydberg states of DyO using an infrared free electron laser. Vibrational excitation is detected either by resonance enhanced multiphoton ionisation from X8( = 1) or by autoionisation of Rydberg states converging to DyO( = 1). For most heavy molecules, the large spectral width of an infrared free electron laser does not allow for rotational resolution.
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