High brightness of upconversion luminescence (UCL) for a thinner layer of UC nanoparticles is significant for routine applications of effective trademark anticounterfeiting technology. In this work, efficient UCL of NaYF:Yb,Er/Tm was realized by combining a TaO dielectric layer on the cyclical island silver films supported by poly(methyl methacrylate) opal photonic crystals (PCs). The synergistic modulation of localized surface plasmon resonance and PC effect results in a significant improvement of the local electromagnetic field and an optimum UC enhancement of 145 folds. Furthermore, colorful pattern nanoprinting has been applied to this composite and used for trademark anticounterfeiting. The combination of angle-dependent PC effect and infrared-to-visible UCL represents a more advanced anticounterfeiting technique.
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http://dx.doi.org/10.1021/acsami.7b10015 | DOI Listing |
ACS Nano
June 2020
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, 150001 Harbin, People's Republic of China.
Optical anticounterfeiting, typically using luminescent materials to encode and unveil hidden patterns, plays an essential role in countering fraud in trademark, document security, food industry, and public safety. However, this technique is often realized through color-encoded fashion and in the visible range, preventing high-order encryption as well as visualization through scattering layers. Here, we describe a set of shortwave infrared (SWIR)-emitting lanthanide-doped nanoparticles with precisely controlled luminescence lifetime, which can be utilized as temporary codes for multilevel anticounterfeiting through opaque layers.
View Article and Find Full Text PDFNat Commun
January 2020
Weldon School of Biomedical Engineering, Purdue University, West Lafayette, Indiana, 47907, USA.
Counterfeit medicines are a fundamental security problem. Counterfeiting medication poses a tremendous threat to patient safety, public health, and the economy in developed and less developed countries. Current solutions are often vulnerable due to the limited security levels.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2019
State Key Laboratory of Solid Lubrication , Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , Lanzhou 730000 , P. R. China.
Anticounterfeiting is a highly required technique to protect the product and the consumer rights in the modern society. The conventional luminescent anticounterfeiting is based on downconversion luminescence excited by an ultraviolet light, which is easy to be faked. In this work, we realized six luminescent modes in a niobate-based structure (LiNbO:RE, RE = Pr, Tm, Er, Yb), in which photostimulated luminescence of LiNbO:Pr, and upconversion luminescence color evolution of LiNbO:Er were first presented.
View Article and Find Full Text PDFNanoscale
August 2018
State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Road, Dalian 116024, P.R. China.
The photonic stop bands of colloidal crystals appear as structural colors, which are potentially useful for display devices, colorimetric sensors, optical filters, paints, and photonic papers. However, low durability and pale colors caused by the undesired scattering of light seriously limit their practical applications. In this article, a polydimethylsiloxane (PDMS)/photonic crystal (PC)/PDMS sandwich structure was designed as a free standing structural colored film with good durability and brilliant color.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2017
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, and ‡College of Physics, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China.
High brightness of upconversion luminescence (UCL) for a thinner layer of UC nanoparticles is significant for routine applications of effective trademark anticounterfeiting technology. In this work, efficient UCL of NaYF:Yb,Er/Tm was realized by combining a TaO dielectric layer on the cyclical island silver films supported by poly(methyl methacrylate) opal photonic crystals (PCs). The synergistic modulation of localized surface plasmon resonance and PC effect results in a significant improvement of the local electromagnetic field and an optimum UC enhancement of 145 folds.
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