An unconventional cleavage of an unstrained carbon-carbon bond in allylic alcohols can be induced by the use of -fluorobenzenesulfonimide (NFSI) under catalyst-free conditions. By using this simple procedure, a wide range of functionalized -fluoroalkenes can be accessed in high yield and selectivity from cyclic and acyclic allylic alcohols.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578365 | PMC |
| http://dx.doi.org/10.1039/c7sc00483d | DOI Listing |
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