AI Article Synopsis
- Phosphonium ionic liquids (ILs) were utilized for the organic modification of layered double hydroxide (LDH) using tetra-alkylphosphonium cations paired with different anions.
- Two concentrations (2 and 5 wt %) of these modified LDHs were blended into a poly(butylene adipate-terephthalate) (PBAT) matrix via melt extrusion.
- The resulting PBAT/IL-modified-LDH composites demonstrated improved mechanical properties, reduced water vapor permeability, and slightly decreased crystallinity compared to pure PBAT.
Article Abstract
In this work, phosphonium ionic liquids (ILs) based on tetra-alkylphosphonium cations combined with carboxylate, phosphate and phosphinate anions, were used for organic modification of layered double hydroxide (LDH). Two different amounts (2 and 5 wt %) of the organically modified LDHs were mixed with poly(butylene adipate--terephthalate) (PBAT) matrix by melt extrusion. All prepared PBAT/IL-modified-LDH composites exhibited increased mechanical properties (20-50% Young's modulus increase), decreased water vapor permeability (30-50% permeability coefficient reduction), and slight decreased crystallinity (10-30%) compared to the neat PBAT.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5666462 | PMC |
| http://dx.doi.org/10.3390/nano7100297 | DOI Listing |
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