A novel metallo-organic ligand [RuL] with four uncomplexed coordination sites was created, and upon treatment with Zn generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru, two Fe, and two Zn ions precisely located in the different edges. This strategy opens the door to novel designer 3D polymetallic constructs capable of diverse applications.
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| http://dx.doi.org/10.1039/c7cc05577c | DOI Listing |
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