Interfacial defect shedding is the most recent known mechanism for defect formation in a thermally driven isotropic-to-nematic phase transition. It manifests in nematic-isotropic interfaces going through an anchoring switch. Numerical computations in planar geometry established that a growing nematic droplet can undergo interfacial defect shedding, nucleating interfacial defect structures that shed into the bulk as +1/2 point defects. By extending the study of interfacial defect shedding in a growing nematic droplet to larger length and time scales, and to three dimensions, we unveil an oscillatory growth mode involving shape and anchoring transitions that results in a controllable regular distributions of point defects in planar geometry, and complex structures of disclination lines in three dimensions.
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http://dx.doi.org/10.1103/PhysRevE.96.022707 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Inner Mongolia University, Daxue West Road, 010021, Hohhot, CHINA.
Crystal-facet heterojunction engineering of mesoporous nanoreactors with highly redox-active represents an efficacious strategy for the transformation of CO2 into valuable C2 products (e.g., C2H4).
View Article and Find Full Text PDFACS Nano
January 2025
Ministry of Industry and Information Technology Key Lab of Micro-Nano Optoelectronic Information System, Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems, Harbin Institute of Technology (Shenzhen), Shenzhen, Guangdong 518055, China.
The power conversion efficiencies (PCEs) of polycrystalline perovskite solar cells (PC-PSCs) have now reached a plateau after a decade of rapid development, leaving a distinct gap from their Shockley-Queisser limit. To continuously mitigate the PCE deficit, nonradiative carrier losses resulting from defects should be further optimized. Single-crystal perovskites are considered an ideal platform to study the efficiency limit of perovskite solar cells due to their intrinsically low defect density, as demonstrated in bulk single crystals.
View Article and Find Full Text PDFBiomaterials
January 2025
Prometheus Division of Skeletal Tissue Engineering, KU Leuven, O&N1, Herestraat 49, PB 813, 3000, Leuven, Belgium; Skeletal Biology and Engineering Research, KU Leuven, ON1 Herestraat 49, PB 813, 3000, Leuven, Belgium. Electronic address:
Self-assembled cartilaginous microtissues provide a promising means of repairing challenging skeletal defects and connective tissues. However, despite their considerable promise in tissue engineering, the mechanical response of these engineered microtissues is not well understood. Here we examine the mechanical and viscoelastic response of progenitor cell aggregates formed from human primary periosteal cells and the resulting cartilaginous microtissues under large deformations as might be encountered in vivo.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education/Shandong Province, State Key Laboratory of Biobased Material and Green Papermaking, Faculty of Light Industry, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China.
The supported RuO catalysts are known for their synergistic and interfacial effects, which significantly enhance both catalytic activity and stability. However, polymer-supported RuO catalysts have received limited attention due to challenges associated with poor conductivity. In this study, we successfully synthesized the RuO-polytetrafluoroethylene (PTFE) catalyst via a facile annealing process.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310058, P. R. China.
Building 2D/3D heterojunction is a promising approach to passivate surface defects and improve the stability of perovskite solar cells (PSCs). Developing effective methods to build high-quality 2D/3D heterojunction is in demand. The formation of 2D/3D heterojunction involves both the diffusion of 2D spacer molecules and phase transition from 3D to 2D structure.
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