The time-resolved luminescence spectra and the lifetimes of eighteen black writing inks were measured to differentiate pen ink on altered documents. The spectra and lifetimes depended on the samples. About half of the samples only exhibited short-lived luminescence components on the nanosecond time scale. On the other hand, the other samples exhibited short- and long-lived components on the microsecond time scale. The samples could be classified into fifteen groups based on the luminescence spectra and dynamics. Therefore, luminescence lifetime can be used for the differentiation of writing inks, and luminescence lifetime imaging can be applied for the examination of altered documents.
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http://dx.doi.org/10.1016/j.forsciint.2017.09.003 | DOI Listing |
Nano Lett
January 2025
Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China.
Lanthanide-doped fluoride nanocrystals have emerged as promising tools in biomedicine, yet their applications are still limited by their low luminescence efficiency. Herein, we developed highly efficient lithium-based core-shell-shell (CSS) nanoprobes (NPs) featuring a rhombic active domain and a spherical inert protective shell. By introducing Yb as an energy transfer bridge and optimizing the CSS design, a remarkable 1643-fold enhancement in visible emission and a 33-fold increase in NIR emission are achieved compared to original nanoparticles.
View Article and Find Full Text PDFNat Commun
December 2024
Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian, China.
Highly efficient perovskite solar cells (PSCs) in the n-i-p structure have demonstrated limited operational lifetimes, primarily due to the layer-to-layer ion diffusion in the perovskite/doped hole-transport layer (HTL) heterojunction, leading to conductivity drop in HTL and component loss in perovskite. Herein, we introduce an ultrathin (~7 nm) p-type polymeric interlayer (D18) with excellent ion-blocking ability between perovskite and HTL to address these issues. The ultrathin D18 interlayer effectively inhibits the layer-to-layer diffusion of lithium, methylammonium, formamidium, and iodide ions.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Analytical & Testing Center, Chengdu, 610064, China.
Aqueous-phase phosphors are of utmost importance for a myriad of applications. However, the emission wavelengths of the current aqueous organic room-temperature phosphorescent (RTP) materials are limited to green and red bands, while the blue part is rarely reported, thus limiting the development of a full-color RTP system. Theoretically, carboxylated benzene is expected to be blue phosphorescence-emissive, but only green phosphorescence is observed in solid, due to the strong intermolecular π-π stacking that decreases the energy gap.
View Article and Find Full Text PDFChem Catal
November 2024
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
The use of visible light to drive chemical transformations has a history spanning over a century. However, the development of photo-redox catalysts to efficiently harness light energy is a more recent advancement, evolving over the past two decades. While ruthenium and iridium-based photocatalysts dominate due to their photostability, long excited-state lifetimes, and high redox potentials, concerns about sustainability and cost have shifted attention to first-row transition metals.
View Article and Find Full Text PDFInorg Chem
December 2024
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Metal-organic frameworks (MOFs) with long persistent luminescence (LPL) have attracted extensive research attention due to their potential applications in information encryption, anticounterfeiting technology, and security logic. The strategic combinations of organic phosphor linkers and metal ions lead to tremendous frameworks, which could unveil many undiscovered properties of organics. Here, the synthesis and characterization of a three-dimensional MOF (Cd-MOF) is reported, which demonstrates enhanced blue photoluminescence and a phosphorescent lifetime of 124 ms as compared to the pristine linker (HL) under ambient conditions due to the scaffolding and heavy-atom effects of metal chains in the framework.
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