Due to their industrial relevance, phenolic compounds (PC) are amongst the most common organic pollutants found in many industrial wastewater effluents. The potential detrimental health and environmental impacts of PC necessitate their removal from wastewater to meet regulatory discharge standards to ensure meeting sustainable development goals. In recent decades, one of the promising, cost-effective and environmentally benign techniques for removal of PC from water streams has been adsorption onto sewage sludge (SS)-based activated carbon (SBAC). This is attributed to the excellent adsorptive characteristics of SBAC and also because the approach serves as a strategy for sustainable management of huge quantities of different types of SS that are in continual production globally. This paper reviews conversion of SS into activated carbons and their utilization for the removal of PC from water streams. Wide ranges of topics which include SBAC production processes, physicochemical characteristics of SBAC, factors affecting PC adsorption onto SBAC and their uptake mechanisms as well as the regeneration potential of spent SBAC are covered. Although chemical activation techniques produce better SBAC, yet more research work is needed to harness advances in material science to improve the functional groups and textural properties of SBAC as well as the low performance of physical activation methods. Studies focusing on PC adsorptive performance on SBAC using continuous mode (that are more relevant for industrial applications) in both single and multi-pollutant aqueous systems to cover wide range of PC are needed. Also, the potentials of different techniques for regeneration of spent SBAC used for adsorption of PC need to be assessed in relation to overall economic evaluation within realm of environmental sustainability using life cycle assessment.
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http://dx.doi.org/10.3390/ijerph14101094 | DOI Listing |
Materials (Basel)
December 2024
Institute of Nuclear Physics Polish Academy of Sciences, 31-342 Krakow, Poland.
The resistivity of the silica SBA-15 type can be significantly improved by forming a thin layer of carbon on the pore surface. This is possible through the carbonization reaction of a surfactant used as a structure-directing agent in the synthesis of mesostructured silica materials. The synthesis of this type of silica-carbon composite (SBA-C) is based on the use of sulfuric acid to create a carbon layer from surfactant molecules encapsulated in silica mesopores.
View Article and Find Full Text PDFOrg Biomol Chem
January 2025
Ocean College, Zhejiang University, 1 Zheda Rd., Zhoushan 316021, China.
Fluorinases represent the only known biological catalysts capable of forming carbon-fluorine bonds, but their slow catalytic rate limits their broader application. In this study, two fluorinases, FlA and FlA, were identified from a pool of 12 718 nonredundant proteins using a genome-mining approach, with FlA showing high catalytic activity. Both newly identified fluorinases contain a Phe50 residue in place of the Trp50 typically found in fluorinases.
View Article and Find Full Text PDFNano Lett
December 2024
School of Physics and Mechatronic Engineering, Guizhou Minzu University, Guiyang 550025, China.
Int J Biol Macromol
August 2024
Departamento de Engenharia Química, Universidade Federal do Ceará, Campus do Pici, Fortaleza, Ceará, Brazil. Electronic address:
Heterogeneous biocatalysts were prepared by adsorbing T. lanuginosus lipase (TLL) onto uncalcined (SBAUC-TLL) and calcined (SBAC-TLL) SBA-15, using ammonium fluoride as a pore expander to facilitate TLL immobilization. At an enzyme load of 1 mg/g, high immobilization yields (>90 %) and recovered activities (>80 % for SBAUC-TLL and 70 % for SBAC-TLL) were achieved.
View Article and Find Full Text PDFJ Environ Manage
May 2024
Department of Civil Engineering, University of British Columbia, 6250 Applied Science Lane, Vancouver, BC, V6T 1Z4, Canada. Electronic address:
Perfluoroalkyl acids (PFAAs) are ubiquitous in nature and pose serious health risks to humans and animals. Limiting PFAA exposure requires novel technology for their effective removal from water. We investigated the efficacy of biosolid-based activated carbon (Bio-SBAC) in removing frequently detected PFAAs and their precursor fluorotelomer compounds at environmentally relevant concentrations (∼50 μg/L).
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