Methane (CH) oxidation in soil reduces the concentration of this greenhouse gas due to the activity of methanotrophic bacteria. This process is influenced by chemical and physical parameters of soil. We tested the methanotrophic activity of selected mineral soils (Mollic Gleysol, Haplic Podzol, Eutric Cambisol) contaminated with lead (Pb) under different soil water potentials (pF 0; 2.2; 3.2). The heavy metal was added as PbCl in two doses. Together with the initial content of Pb in soils, the final contents of heavy metal in different soils were 11.6 and 30.8 mg kg in Eutric Cambisol, 7.1 and 26.3 mg kg in Haplic Podzol, and 12.2 and 31.4 mg kg in Mollic Gleysol (dry mass of the soil is specified in all cases). The results showed relatively low sensitivity of methane oxidation to the addition of the heavy metal. The major factor controlling this process was soil water content, which in most cases turned out to be the most optimal at pF = 2.2.
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http://dx.doi.org/10.1007/s11356-017-0195-8 | DOI Listing |
Environ Res
January 2025
Department of Civil and Smart Construction Engineering, Shantou University, Shantou, Guangdong 515063, China. Electronic address:
Landfill gas (LFG) has become the second-largest anthropogenic source of methane (CH) emissions globally. CH is the second most significant greenhouse gas after carbon dioxide (CO), thus it is crucial to mitigate the methane emission of landfills. The soil in landfill cover layers is rich in methane-oxidizing bacteria (MOB), which use CH as their sole carbon and energy source.
View Article and Find Full Text PDFWaste Manag
January 2025
BioEngine Research Team on Green Process Engineering and Biorefineries, Chemical Engineering Department, Université Laval, Pavillon Adrien-Pouliot 1065, av. de la Médecine, Québec, Québec, Canada; CentrEau, Centre de recherche sur l'eau, Université Laval, 1065 Avenue de la Médecine, Québec, QC, G1V 0A6, Canada. Electronic address:
Despite advances in anaerobic digestion (AD), full-scale implementation faces significant challenges, particularly during the start-up phase, where inoculum selection is crucial. This study examines the impact of inoculum choice on the operational and economic performance of thermophilic digesters during the start-up phase. Methanogenic reactors R3 and R4 were inoculated with digested sludge (DiS) and diluted sewage sludge (DSS), respectively, and fed with hydrolyzed source-sorted organic fraction of municipal solid waste (SS-OFMSW) and thickened sewage sludge, which were processed in R1 and R2, serving as acidogenic reactors.
View Article and Find Full Text PDFSci Technol Adv Mater
December 2024
Department of Life, Environment and Applied Chemistry, Fukuoka Institute of Technology, Fukuoka, Japan.
Alkaline-earth metal oxides with the rocksalt structure, which are simple ionic solids, have attracted attention in attempts to gain fundamental insights into the properties of metal oxides. The surfaces of alkaline-earth metal oxides are considered promising catalysts for the oxidative coupling of methane (OCM); however, the development of such catalysts remains a central research topic. In this paper, we performed first-principles calculations to investigate the ability of four alkaline-earth metal oxides (MgO, CaO, SrO, and BaO) to catalyze the OCM.
View Article and Find Full Text PDFChemistry
January 2025
Ningbo University, School of Material Science and Chemical Engineering, Rokkakubashi, Kanagawa-ku, Yokohama-shi, Kanagawa, 221-8686, Japan., 315211, Ningbo, CHINA.
Direct oxidation of methane to methanol utilizing molecular oxygen under mild conditions is an important yet challenging process due to the difficulty in activation of methane under such conditions. In this research, we report zeolitic octahedral metal oxides based on cobalt vanadotungstates, which act as the catalysts for oxidation of methane using molecular oxygen as the oxidant without co-reductants at a low temperature of 90 oC even as low as 60 oC. This catalytic process results in the high-yield production of methanol as the major product.
View Article and Find Full Text PDFPLoS One
January 2025
Environmental Molecular Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, United States of America.
Coastal wetlands, including freshwater systems near large lakes, rapidly bury carbon, but less is known about how they transport carbon either to marine and lake environments or to the atmosphere as greenhouse gases (GHGs) such as carbon dioxide and methane. This study examines how GHG production and organic matter (OM) mobility in coastal wetland soils vary with the availability of oxygen and other terminal electron acceptors. We also evaluated how OM and redox-sensitive species varied across different size fractions: particulates (0.
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