Crystal structure of 1-[2-(4-nitro-phen-yl)-4,5-diphenyl-1-imidazol-1-yl]propan-2-ol.

Acta Crystallogr E Crystallogr Commun

Kirkuk University, College of Education, Department of Chemistry, Kirkuk, Iraq.

Published: September 2017

The title compound, CHNO, crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol-ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents are 42.51 (9), 45.41 (9) and 56.92 (8)°, respectively. Comparable data for molecule 2 are 39.36 (10), 34.45 (11) and 60.34 (8)°, respectively. The rings at the 2-positions carry -nitro substituents that subtend dihedral angles of 12.9 (4)° in mol-ecule 1 and 11.7 (4)° in mol-ecule 2 to their respective benzene ring planes. The imidazole rings also have propan-2-ol substituents on the 1-N atoms, which adopt extended conformations for the N-C-C-C chains. In the crystal, classical O-H⋯N hydrogen bonds combine with C-H⋯O, C-H⋯N and C-H⋯π(ring) hydrogen bonds and stack the molecules along the -axis direction.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588590PMC
http://dx.doi.org/10.1107/S2056989017011057DOI Listing

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