The title compound, CHBFP {alternative name: triphen-yl[(tri-fluoro-boran-yl)meth-yl]phosphanium}, was formed by the reaction of tri-phenyl-phosphine with potassium iodo-methyl-tri-fluoro-borate. The mol-ecule features a nearly staggered conformation along the P-C bond and a less than staggered conformation along the C-B bond. In the crystal, weak C-H⋯F hydrogen bonds between the -phenyl C-H groups and the tri-fluoro-borate B-F groups form chains of (16) rings along [100]. These chains are are further stabilized by weak C-H⋯π inter-actions. A weak intra-molecular C-H⋯F hydrogen bond is also observed.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835 | PMC |
http://dx.doi.org/10.1107/S2056989017009884 | DOI Listing |
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