The synthesis and supramolecular polymerization of a ureidopyrimidinone-based Sauvage-type [2]catenane is reported. The monomer synthesis explores many routes using the elegant metathesis catalysts of Bob Grubbs, yielding a catenane with one ureidopyrimidinone in each cycle. The supramolecular polymer obtained features both mechanical bonds and quadruple hydrogen bonding connections.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575501 | PMC |
| http://dx.doi.org/10.1002/pola.28694 | DOI Listing |
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