The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks.

Chem Commun (Camb)

Supramolecular Machines and ARchitectures Team, Institut des Biomolécules Max Mousseron (IBMM), Univ. Montpellier, UMR 5247 CNRS, ENSCM, Case Courrier 1706, Bâtiment Chimie (17), 3ème étage, Faculté des Sciences, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France.

Published: October 2017

A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain an ammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread.

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http://dx.doi.org/10.1039/c7cc06598aDOI Listing

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