Electrostatic fields tune the ground state of interfaces between complex oxide materials. Electronic properties, such as conductivity and superconductivity, can be tuned and then used to create and control circuit elements and gate-defined devices. Here we show that naturally occurring twin boundaries, with properties that are different from their surrounding bulk, can tune the LaAlO/SrTiO interface 2DEG at the nanoscale. In particular, SrTiO domain boundaries have the unusual distinction of remaining highly mobile down to low temperatures, and were recently suggested to be polar. Here we apply localized pressure to an individual SrTiO twin boundary and detect a change in LaAlO/SrTiO interface current distribution. Our data directly confirm the existence of polarity at the twin boundaries, and demonstrate that they can serve as effective tunable gates. As the location of SrTiO domain walls can be controlled using external field stimuli, our findings suggest a novel approach to manipulate SrTiO-based devices on the nanoscale.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1038/nmat4966 | DOI Listing |
Sci Rep
January 2025
Research Institute of Interdisciplinary Science, School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, 523808, China.
Manufacturing of metallic components using additive manufacturing technique is of great interest for the industrial applications. Here, the mechanical and microstructural responses of a 316 L stainless steel (316LSS) built by selective laser melting (SLM) with XOY and XOZ directions were revealed by performing in situ neutron diffraction tensile tests. The tensile strength of the XOY-printed samples reaches 700 MPa, while the tensile strength of the XOZ-printed samples is less than 600 MPa.
View Article and Find Full Text PDFSmall
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China.
Fivefold twins are extensively present in nanoparticles and nanowires, enhancing their performance in physical, chemical, and mechanical properties. However, a deep insight into the correlation between mechanical properties and fivefold twins in bulk nanograined materials is lacking due to synthesis difficulties. Here, a bulk fivefold-twinned nanograined Ni is synthesized via electrodeposition.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Huazhong University of Science and Technology, School of Materials Science and Engineering, 1037 Luoyu Road, 430074, Wuhan, CHINA.
Organics electrooxidation coupled hydrogen production has attracted increasing attention due to the low operation voltage. Nevertheless, the spontaneous production of hydrogen coupled with organics valorization remains challenging. Herein, we develop ultrathin Au/Pt twin nanowire (NW) catalysts for both electrochemical glucose oxidation and hydrogen evolution reaction towards a spontaneous hydrogen production system.
View Article and Find Full Text PDFACS Nano
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.
Nanotwinned materials have recently attracted intense interest since they often exhibit excellent mechanical properties that are far superior to those of the corresponding single crystals. However, how nanotwinned structures affect the physical properties of functional materials remains almost unexplored. In this study, we demonstrate ferrimagnetism in a nanotwinned antiferromagnetic CrO thin film.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Materials Chemistry, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.
Nanoparticulate electrocatalysts for the oxygen reduction reaction are structurally diverse materials. Scanning transmission electron microscopy (STEM) has long been the go-to tool to obtain high-quality information about their nanoscale structure. More recently, its four-dimensional modality has emerged as a tool for a comprehensive crystal structure analysis using large data sets of diffraction patterns.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!