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Scavenger templates: a systems chemistry approach to the synthesis of porphyrin-based molecular wires. | LitMetric

Scavenger templates: a systems chemistry approach to the synthesis of porphyrin-based molecular wires.

Chem Commun (Camb)

Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Oxford, OX1 3TA, UK.

Published: September 2017

AI Article Synopsis

  • A hexa-pyridyl template acts as a scavenger to help create a linear porphyrin dodecamer from a mix of linear hexamers.
  • The template prevents unwanted polymer formation by quickly cyclizing the fully deprotected hexamer.
  • As a result, this process promotes the production of the desired linear dodecamer.

Article Abstract

A hexa-pyridyl template can be used as a scavenger to facilitate the synthesis of a linear porphyrin dodecamer from a mixture of linear hexamers with one or two terminal reactive groups. The template suppresses polymer formation by rapidly cyclizing the fully deprotected hexamer, thus up-regulating formation of the linear dodecamer.

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Source
http://dx.doi.org/10.1039/c7cc04289bDOI Listing

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