Purpose: To investigate the effect of neodymium-doped yttrium aluminum garnet (Nd:YAG) laser irradiation on the surface properties and bond strength of zirconia ceramics.
Materials And Methods: Forty-eight zirconia ceramic pieces (4 × 4 × 1 mm ) were divided into four groups according to surface treatment as follows: two control groups (no treatment) for resin bonding (CRC) and glass ionomer (GI) bonding (CGC); two laser treatment groups (Nd:YAG irradiation, 3 W, 200 MJ, 10 Hz, 180 μs) for resin bonding (LRC) and GI bonding (LGC). The ceramics in the control groups and the laser groups were distinguished by the application of different cements (resin cement and GI). Following surface treatments, the specimens were cemented to human dentin with resin cement and GI. After bonding, the shear bond strength (SBS) of the ceramic to dentin was measured, and the failure mode of each specimen was analyzed using a stereomicroscope. A one-way ANOVA compared the average bond strength of the four groups. Pairwise comparisons among the groups were performed using the Games-Howell test. The level of significance was set at 0.05.
Results: The means (± standard deviation) of SBS values in the CRC, CGC, LRC, and LGC groups were 3.98 ± 1.10, 1.66 ± 0.59, 10.24 ± 2.46, and 2.21 ± 0.38 MPa, respectively. Data showed that the application of the Nd:YAG laser resulted in a significantly greater SBS of the resin cement to the zirconia ceramics (p < 0.001). The highest bond strength was recorded in the LRC group. In the CRC group, 75% of the failures were of the adhesive type, compared with 66.7% and 83.3% in the LRC and LGC groups, respectively. In the CGC group, all failures were adhesive.
Conclusions: Pretreatment of zirconia ceramic via Nd:YAG laser improves the bond strength of the resin cement to the zirconia ceramic. GI cement does not provide sufficient bond strength of zirconia ceramics to dentin.
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http://dx.doi.org/10.1111/jopr.12651 | DOI Listing |
Nano Lett
January 2025
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China.
Pnictogen bond (PnB) occurring on the group-15 elements is recognized as σ- or π-hole-based interaction that has garnered attention in the fields of anion recognition and organocatalysis. Due to the polyvalent feature of pnictogens and high directionality, PnB possesses potential in the design of convergent coassembled materials with acceptors containing lone pair electrons or anions, which however is rarely explored so far. Herein, we unveil the role of antimony (Sb)-based PnB donors in producing self-assembled chiroptical materials with lone pair electron containing acceptors.
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Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child Health (NEUROFARBA), University of Florence, Sesto Fiorentino, Firenze, Italy.
2,2'-Thio-bis(4,6-dichlorophenol), namely bithionol, is a small molecule endowed with a multifaceted bioactivity. Its peculiar polychlorinated phenolic structure makes it a suitable candidate to explore its potentialities in establishing interaction patterns with enzymes of MedChem interest, such as the human carbonic anhydrase (hCA) metalloenzymes. Herein, bithionol was tested on a panel of specific hCAs through the stopped-flow technique, showing a promising micromolar inhibitory activity for the hCA II isoform.
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Laboratoire Sciences et Ingénierie de la Matiére Molle, ESPCI Paris, CNRS, PSL University, Paris, France.
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View Article and Find Full Text PDFEur J Oral Sci
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Department of Basic Sciences, Biomedical Stomatology Research Group, Faculty of Dentistry, Universidad de Antioquia U de A, Medellín, Colombia.
J Vis Exp
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School of Engineering and Materials Science, Queen Mary University of London.
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