This study investigated the feasibility of using polycaprolactone (PCL) nanofiber-based air filters to capture PM2.5 particles emitted from fused deposition modeling (FDM) 3D printing. Generation and aggregation of emitted particles were investigated under different testing environments. The results show that: (1) the PCL nanofiber membranes are capable of capturing particle emissions from 3D printing, (2) relative humidity plays a signification role in aggregation of the captured particles, (3) generation and aggregation of particles from 3D printing can be divided into four stages: the PM2.5 concentration and particles size increase slowly (first stage), small particles are continuously generated and their concentration increases rapidly (second stage), small particles aggregate into more large particles and the growth of concentration slows down (third stage), the PM2.5 concentration and particle aggregation sizes increase rapidly (fourth stage), and (4) the ultrafine particles denoted as "building unit" act as the fundamentals of the aggregated particles. This work has tremendous implications in providing measures for controlling the particle emissions from 3D printing, which would facilitate the extensive application of 3D printing. In addition, this study provides a potential application scenario for nanofiber-based air filters other than laboratory theoretical investigation.
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http://dx.doi.org/10.1038/s41598-017-10995-7 | DOI Listing |
Chemistry
December 2024
Universitat Duisburg-Essen, Institute of organic chemistry, Universitätsstraße 7, 45117, Essen, GERMANY.
In recent years, researchers studying fluorogenic samples have steadily shifted from using large, expensive, poorly soluble fluorophores with complex synthetic sequences to smaller, simpler p scaffolds with low molecular weight. This research article presents an in-depth study of the photophysical properties of five bridged single-benzene-based fluorophores (SBBFs) investigated for their solution and solid-state emission (SSSE) properties. The compounds O4, N1O3, N2O2, N3O1, and N4 are derived from a central terephthalonitrile core and vary in the amount of oxygen and nitrogen bridging atoms.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Institute of Optoelectronics Technology, Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Beijing 100044, China.
This work explores the carrier recombination dynamics of AC-driven quantum dot (QD) light-emitting diodes (AC-QLEDs) and proposes their application in the field of electric field contactless detection. Different sequences of green QD (GQD)/red QD (RQD) bilayer thin films as the emission layer of AC-QLEDs were fabricated via film transfer printing to ensure the complete morphology of each layer. AC-QLEDs with the emission layer as the sequence of GQD + RQD (GR-QLEDs) show a significantly enhanced carrier recombination efficiency due to its stable energy level structure, achieving the highest peak brightness ever recorded for vertically emitting brightness of 1648.
View Article and Find Full Text PDFSmall Methods
December 2024
Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Thiruvananthapuram, 695019, India.
To counter economic terrorism by preventing counterfeit currency, documents and high-value commercial products, new-generation security inks with multiple safety features are required. Herein, color-tunable pyrylium and pyridinium dye-encapsulated polymethyl methacrylate (PMMA) colloidal microspheres are reported to exhibiting brilliant emission and photonic properties. A combination of the PMMA colloidal photonic ink having structural color variation and the dye-encapsulated colloidal photonic ink with fluorescence modulation is used for security labeling.
View Article and Find Full Text PDFSmall
December 2024
Institute of Micro- and Nanotechnologies MacroNano, Microsystems Technology Group, Technische Universität Ilmenau, Max-Planck-Ring 12, 98693, Ilmenau, Germany.
3D printing down to the nanoscale remains a significant challenge. In this paper, the study explores the use of scanning probes that emit low-energy electrons (<100 eV) coupled with the localized injection and electron-induced decomposition of precursor molecules, for the precise localized deposition of 3D nanostructures. The experiments are performed inside the chamber of a scanning electron microscope (SEM), enabling the use of the in-built gas injector system (GIS) with gaseous naphthalene precursor for carbon deposition, as well as immediate inspection of the deposits by SEM.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Eco-Friendly Circular Advanced Materials and Additive Manufacturing (ECAM) Lab, Department of Mechanical and Manufacturing Engineering, Ontario Tech University, Oshawa, ON L1G 0C5, Canada.
The current study explores, for the first time, an eco-friendly solution casting method using a green solvent, ethyl acetate, to prepare feedstock/filaments from polylactic acid (PLA) biopolymer reinforced with carbon nanotubes (CNTs), followed by 3D printing and surface activation for biosensing applications. Comprehensive measurements of thermal, electrical, rheological, microstructural, and mechanical properties of developed feedstock and 3D-printed parts were performed and analyzed. Herein, adding 2 wt.
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