Correction for 'Enhancements in catalytic reactivity and selectivity of homobimetallic complexes containing heteroditopic ligands' by Mark R. D. Gatus et al., Dalton Trans., 2017, 46, 7457-7466.
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http://dx.doi.org/10.1039/c7dt90117h | DOI Listing |
J Org Chem
January 2025
Department of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252059, China.
Multipalladium clusters possess peculiar structures and synergistic effects for reactivity and selectivity. Herein, -symmetric tripalladium clusters (, 0.5 mol %) afford C-regioselective SMCC of 2,4-dibromopyridine with phenylboronic acids or pinacol esters (C:C up to 98:1), in contrast to Pd(OAc) in ligand-free conditions.
View Article and Find Full Text PDFJ Med Chem
January 2025
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.
The hypoxic environment of solid tumors significantly diminishes the therapeutic efficacy of oxygen-dependent photodynamic therapy. Developing efficient photosensitizers that operate photoredox catalysis presents a promising strategy to overcome this challenge. Herein, we report the rational design of two rhenium(I) tricarbonyl complexes ( and ) with electron donor-acceptor-donor configuration.
View Article and Find Full Text PDFLangmuir
January 2025
CSSC Nanjing Lvzhou Environmental Protection Co., Ltd, Nanjing 210039, China.
In this study, the MnFeO@CoS magnetic nanocomposite was prepared by a two-step hydrothermal method and used to catalyze the ozone oxidation degradation of methylene blue. It was characterized by XRD, EDS, SEM, FT-IR, and XPS. The results showed that the introduction of CoS made MnFeO grow uniformly on CoS nanosheets, which effectively prevented the agglomeration of MnFeO.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Department of Functional Materials and Electronics, State Research Institute Centre for Physical Sciences and Technology (FTMC), 10257 Vilnius, Lithuania.
Niobium nanoparticles (NbNPs) have gained attention as promising materials in biomedical applications due to their exceptional biocompatibility, corrosion resistance, and versatility. These nanoparticles offer potential in drug delivery, imaging, and tissue engineering, where their nanoscale properties allow precise interactions with biological systems. Among niobium-based nanomaterials, niobium pentoxide (NbO) is the most extensively studied due to its chemical stability, bioactivity, and optical properties.
View Article and Find Full Text PDFJ Fungi (Basel)
December 2024
College of Food Science and Engineering, Gansu Agricultural University, Lanzhou 730070, China.
Periodic mycelial subculture is a method commonly used for the storage of edible mushrooms, but excessive subculturing can lead to the degeneration of strains. In this study, the strain V971(M0) was successively subcultured on PDA medium every 4 days, and one generation of strains was preserved every 4 months. Thus, five generations of subcultured strains (M1-M5) were obtained after 20 months of mycelial subculturing, their production traits were determined, and transcriptomic analysis was performed using RNA-seq; the differentially expressed genes were verified via RT-qPCR.
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