This paper presents analytical and experimental techniques for absolute determination of the acoustic nonlinearity parameter (β) in fluids using focused transducers. When focused transducers are used for β measurements, the geometrical and mechanical calibrations are generally required for accurate determination of the receiver transfer function from which the absolute pressure can be calculated. The fundamental and second harmonic wave amplitudes in harmonic generation measurements should be modified to account for beam diffraction and material absorption. All these issues are resolved in this study and the proposed technique is validated through the β measurement in water. An experimental method is developed to determine the effective radius and focal length of focused transducers. A simplified self-reciprocity calibration procedure for a broadband focused receiver is described. The diffraction and attenuation corrections for the fundamental and second harmonic waves are explicitly derived using the multi-Gaussian beam model, and the effects on the β determination are discussed. When the diffraction and attenuation corrections are all properly made, the measurement of β over a large range of propagation distances is possible with errors less than 8%.
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http://dx.doi.org/10.1121/1.4999328 | DOI Listing |
Molecules
December 2024
Ruđer Bošković Institute, Bijenička Cesta 54, 10000 Zagreb, Croatia.
This study examines the influence of ligand design on the structural, optical, and electrical properties of copper-based coordination complexes. Ligands HL and HL were synthesized via the reaction of 5-nitrosalicylaldehyde with 2-hydroxy- or 4-hydroxybenzhydrazide. HL was obtained from the reaction of carbohydrazide and salicylaldehyde, while HL was prepared by condensing 4-methoxysalicylaldehyde with thiocarbohydrazide.
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January 2025
Department of Physics, Yazd University, Yazd, Iran.
Polymer nanocomposites have been investigated as lightweight and suitable alternatives to lead-based clothing. The present study aims to fabricate flexible, lead-free, X-ray-shielding composites using a polyvinyl chloride (PVC) matrix and different nanostructures. Four different nanostructures containing impure tungsten oxide, tungsten oxide (WO), barium tungstate (BaWO), and bismuth tungstate (BiWO) were synthesized through various methods.
View Article and Find Full Text PDFSci Data
January 2025
Energy Storage & Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA.
Further improvements to lithium-ion and emerging battery technologies can be enabled by an improved understanding of the chemistry and working mechanisms of interphases that form at electrochemically active battery interfaces. However, it is difficult to collect and interpret spectra of interphases for several reasons, including the presence of a variety of compounds. To address this challenge, we herein present a vibrational spectroscopy and X-ray diffraction data library of ten compounds that have been identified as interphase constituents in lithium-ion or emerging battery chemistries.
View Article and Find Full Text PDFPharmaceutics
November 2024
Pharmacy Discipline, School of Clinical Sciences, Faculty of Health, Queensland University of Technology, Brisbane, QLD 4000, Australia.
This study explores the development and characterization of spray-dried composite microparticles consisting of levofloxacin (LVX, a broad-spectrum antibiotic), and ambroxol (AMB, a mucolytic agent that has antibacterial and antibiofilm properties), for the intended application of the drug against lower respiratory tract infections (LRTIs). A range of LVX to AMB mass ratios (1:1, 1:0.5, and 1:0.
View Article and Find Full Text PDFPharmaceutics
November 2024
Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10 000 Zagreb, Croatia.
Nabumetone (NAB) is a poorly soluble nonsteroidal anti-inflammatory prodrug (BCS class II drug) whose solubility is significantly improved by complexation with cyclodextrins (CDs). : The solid complexes, in a 1:1 molar ratio, were prepared by mechanochemical activation by grinding, using β-cyclodextrin (β-CD) and its derivatives, hydroxypropyl- and sulfobutylether-β-cyclodextrin (HP-β-CD and SBE-β-CD). The complexation was confirmed by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and attenuated total reflectance Fourier-transformed infrared spectroscopy (ATR-FTIR).
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