The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-PN is preorganized for the dicopper complex formation with the unique coordination mode in the row of PN corands.
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| http://dx.doi.org/10.1039/c7dt03010j | DOI Listing |
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