Dual-Pore Carbon Shells for Efficient Removal of Humic Acid from Water.

A template-mediated process for the preparation of mesoporous carbon shells with high surface area, dual-pore structure, and excellent performance in the adsorption of humic acid is reported. Their synthesis involves templating phenolic resin against wrinkled silica nanospheres, subsequent carbonization under Ar atmosphere, and final release of dual-pore mesoporous carbon shells by etching the silica templates. An additional silica layer was used to protect the phenolic resin from aggregation during carbonization, and its subsequent removal gives the carbon shells a hydrophilic surface, which significantly improves their dispersity in aqueous media. When used as adsorbents for humic acid removal, the as-prepared dual-pore mesoporous carbon shells show superior adsorption performance to activated carbon.