Sustainability of nutrient requirements for microbial proliferation on a large scale is a challenge in bioremediation processes. This article presents data on biochemical properties of a free cyanide resistant and total nitrogen assimilating fungal isolate from the rhizosphere of (maize) growing in soil contaminated with a cyanide-based pesticide. DNA extracted from this isolate were PCR amplified using universal primers; TEF1-α and ITS. The raw sequence files are available on the NCBI database. Characterisation using biochemical data was obtained using colorimetric reagents analysed with VITEK 2 software version 7.01. The data will be informative in selection of biocatalyst for environmental engineering application.
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http://dx.doi.org/10.1016/j.dib.2017.07.023 | DOI Listing |
Org Biomol Chem
December 2024
State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China.
A TFA-catalyzed dearomative cyanidation of isoquinoline is described, which provides a series of 1-cyanoisoquinolines in high yields under solvent-free conditions. This protocol is operated under mild and environmentally friendly conditions, utilizing readily available and cost-effective starting materials. The reaction features broad functional group compatibility, 100 mmol scale synthesis ability and operational simplicity, making it a significant potential approach for the synthesis of various biologically interesting isoquinolines α C-cyanation.
View Article and Find Full Text PDFAnal Bioanal Chem
December 2024
Institute of Microbiology of the Czech Academy of Sciences, CZ-142 00, Prague, Czech Republic.
Determination of free cyanide (fCN) is required for various industrial, environmental, food, and clinical samples. Enzymatic methods are not widely used in this field despite their selectivity and mild conditions. Therefore, we present here a proof of concept for new spectrophotometric enzymatic assays of fCN.
View Article and Find Full Text PDFMolecules
November 2024
Department of Natural and Environmental Sciences, Faculty of Science, Academic Assembly, University of Toyama, Toyama 930-8555, Japan.
Microorganisms
November 2024
Institute of Plant Protection, Hunan Academy of Agricultural Sciences, Changsha 410125, China.
Dalton Trans
November 2024
School of Integrated Circuit Science and Engineering, Beihang University, Beijing 100191, China.
Certain negative thermal expansion (NTE) materials have been reported to exhibit anomalous lattice thermal conductivity (LTC), making them particularly interesting for theoretical studies. In Zn(CN) and Cd(CN), cyanide bonds have induced great NTE behavior and anharmonicity, making us believe they would exhibit anomalous LTC. To investigate this, we employed first-principles calculations based on density functional theory and solved the linearized Boltzmann transport equation within the relaxation time approximation to calculate the LTC.
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