Comment on "Active sites for CO hydrogenation to methanol on Cu/ZnO catalysts".

Science

Haldor Topsoe A/S, Haldor Topsøes Allé 1, DK-2800 Kongens Lyngby, Denmark.

Published: September 2017

Kattel (Reports, 24 March 2017, p. 1296) report that a zinc on copper (Zn/Cu) surface undergoes oxidation to zinc oxide/copper (ZnO/Cu) during carbon dioxide (CO) hydrogenation to methanol and conclude that the Cu-ZnO interface is the active site for methanol synthesis. Similar experiments conducted two decades ago by Fujitani and Nakamura demonstrated that Zn is attached to formate rather than being fully oxidized.

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Source
http://dx.doi.org/10.1126/science.aan8074DOI Listing

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