Cleanup using two types of agents (S-NH and S-Si) developed by the authors was investigated with the aim of removing interfering substances such as catechin and caffeine to enable analysis of pesticide residues in tea. S-NH and S-Si removed approximately 100% of catechin and caffeine in 6 species of tea. Recoveries of 61 pesticides in tea were tested at the level of 0.1 μg/g, and 44 pesticides showed recovery within the range from 70 to 120%, with RSD of less than 10%. With cleanup using S-NH and S-Si, pesticide residues in tea could be analyzed within two hours.
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http://dx.doi.org/10.3358/shokueishi.58.188 | DOI Listing |
Anal Methods
November 2017
College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China.
A novel method was established using a restricted access material combined with a molecularly imprinted polymer (RAM-MIP) as the sorbent material in solid phase extraction (SPE) for clean-up of α-endosulfan, β-endosulfan, endosulfate, endosulfan-ether, endosulfan lactone, heptachlor, heptachlor--epoxide, and heptachlor--epoxide in pork and gas chromatography (GC) for determination. The RAM-MIP was prepared by precipitation polymerization by using endosulfan as the template, methacrylic acid (MAA) as the monomer, glycidyl methacrylate (GMA) as the pro-hydrophilic co-monomer, ethylene glycol dimethacrylate (EGDMA) as the crosslinker, azobisisobutyronitrile (AIBN) as the initiator, and toluene as the porogen. Ultraviolet spectroscopy (UV) and H-nuclear magnetic resonance (H-NMR) analysis verified that MAA interacted specifically with endosulfan in a ratio of 1 : 1 in the pre-polymerization solution.
View Article and Find Full Text PDFTalanta
January 2025
Department of Electronics and Communication Engineering, Tezpur University, Tezpur, 784028, India. Electronic address:
Detection and analysis of organochlorine pesticides (OCP) residue is getting significant research importance because of their extensive use despite their hazardous effects on the health of people and the ecosystem. Despite the implementation of regulations and bans to safeguard human health and the environment, reports frequently reveal the continued use of these harmful chemicals in quantities exceeding the recommended limits set by regulatory boards. Data on the use of OCP from India, the most populous country, and African countries is not very encouraging.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
School of Precision Instrument and Opto-electronics Engineering, Tianjin University, Tianjin 300072 China. Electronic address:
The detection of pesticide residues in agricultural products is crucial for ensuring food safety. However, traditional methods are often constrained by slow processing speeds and a restricted analytical scope. This study presents a novel method that uses filter-array-based hyperspectral imaging enhanced by a dynamic filtering demosaicking algorithm, which significantly improves the speed and accuracy of detecting pesticide residues.
View Article and Find Full Text PDFFood Chem
January 2025
Key Laboratory of Health Risk Appraisal for Trace Toxic Chemicals of Zhejiang Province, Ningbo Municipal Center for Disease Control and Prevention, Ningbo, Zhejiang 315010, China. Electronic address:
Novel core-shell flower-like polyamine/C dual-functional magnetic titanium dioxide-based oligopolymer (FeO@fTiO-PAPMA/C) microspheres were synthesized and used as a magnetic solid-phase extraction (MSPE) adsorbent to purify 52 pesticides in bayberry samples. The FeO@fTiO-PAPMA/C microspheres were fully characterized and it can obviously improve the purification ability of 52 pesticides in bayberry samples. Coupled to LC-MS/MS, the developed method indicated low limits of detection (LODs) and limits of quantification (LOQs) of 0.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Yunnan Dali Research Institute of Shanghai Jiao Tong University, Dali 671000, China.
Erhai Lake, a vital drinking water source for Dali, a highland agricultural city, faces potential contamination from pesticide residues, yet limited studies have assessed their distribution and impacts. This study investigates the occurrence, transport, partitioning, and ecological risks of pesticides in the lake's dissolved phase (DP), suspended particulate matter (SPM), and sediment (SD) samples collected from 22 sites across different seasons. The results showed significant temporal variations across different media, with spatial variations driven by crop-related patterns.
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