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Cyano-Modified Multi-Resonance Thermally Activated Delayed Fluorescent Emitters towards Pure-Green OLEDs with a CIE y Value of 0.74.
Angew Chem Int Ed Engl
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Shenzhen University, College of Materials Science and Engineering, Xueyuan Avenue, 518000, Shenzhen, CHINA.
The development of pure-green organic emitters with ideal emission peak and ultra-narrow full-widths at half-maximum (FWHMs) remains a formidable challenge. Herein, we report two new green emitters, CNBN and MCNBN, which achieve extremely narrow FWHMs by synergistic rigid π-extension and cyano-substitution for sky-blue multi-resonance thermally activated delayed fluorescence (MR-TADF) core. The introduction of cyano groups induces red-shifts of emission to green region and dramatically minimize the FWHMs.
View Article and Find Full Text PDFPreparation of pH-Responsive Oil-in-Water Microemulsion Using a Full-Bio-Based Surfactant Containing a Dynamic Covalent Bond.
Langmuir
January 2025
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
A novel pH-responsive full-bio-based surfactant (Ca-S) containing a dynamic covalent bond is synthesized using renewable cashew phenol, 5-chloro-2-furanaldehyde, and taurine. The structure of Ca-S is characterized by Fourier transform infrared spectroscopy (FTIR) and H nuclear magnetic resonance (NMR) analysis. Limonene containing oil-in-water (O/W) microemulsions are prepared on the basis of the Ca-S surfactant and are applied to the remediation of oil-contaminated soil under low-energy conditions at ambient temperature.
View Article and Find Full Text PDFSynergistic Effect of Boron Doping and Porous Structures on Titanium Dioxide for Efficient Photocatalytic Nitrate Reduction to Nitrogen in Pure Water.
Inorg Chem
January 2025
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714 China.
Photocatalytic reduction of nitrate to N holds great significance for environmental governance. However, the selectivity of nitrate reduction to N is influenced by sacrificial agents and the kinds of cocatalysts (such as Pt and Ag). The presence of unconsumed sacrificial agents can aggravate environmental pollution, while noble metal-based cocatalysts increase application costs.
View Article and Find Full Text PDFSynthesis of SnO₂/COF green nanomaterials for effective pesticide decomposition and promoting tomato plants growth.
Chem Asian J
January 2025
Northeast Agricultural University, College of Horticulture and Landscape Architecture, CHINA.
In last few decades, the agriculture sector is facing various type of crops diseases originated by crop pests. Among various crops the tomato plant is greatly affected by many pests such as aphids and whiteflies, which are badly decreasing tomato plant yield and effecting its growth. In last few years, various type of pesticides such as Neonicotinoids and Pyrethroids are employed with are badly effecting eco system and water bodies.
View Article and Find Full Text PDFLight is essential for photosynthesis; however, excess light can increase the accumulation of photoinhibitory reactive oxygen species that reduce photosynthetic efficiency. Plants have evolved photoprotective non-photochemical quenching (NPQ) pathways to dissipate excess light energy. In tobacco and soybean (C plants), overexpression of three NPQ genes, e ( V DE), ( P sbS), and ( Z EP), hereafter VPZ, resulted in faster NPQ induction and relaxation kinetics, and increased crop yields in field conditions.
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