(fir), a submontane tree from Central European mountains and uplands, is of special interest for palaeoecological and palaeoclimate interpretations due to its sensitivity to air and soil humidity. Its present distribution limit in the uplands of SE Poland is still a matter of debate. In the Holocene fir expanded to Poland very late, but early fir populations are supposed to occur in the Šumava Mts (Czech Republic). The study aims: to estimate pollen thresholds for fir presence/absence in Bohemia (Czech Republic) and Poland on the basis of modified Tauber pollen traps; to use these thresholds for tracing fir presence in two pollen diagrams from Poland (Słone and Bezedna lakes) in the border zone between the Roztocze region (with fir forest stands today) and Polesie (where fir has never played an important role); and to investigate how the percentage presence/absence threshold can be used to trace the occurrence and abundance of fir trees in the Šumava Mts based on the pollen diagrams of Rokytecká slat' and Mrtvý luh. The fir pollen thresholds estimated in terms of PAR (pollen accumulation rates or pollen influx) range from 843 (grains cm year) (Roztocze) to 61 (Krkonoše) and 49 (Šumava). Percentage thresholds range from 0.3% in Krkonoše where fir trees are not present within 4 km to 22% in fir-dominated woodland of the Roztocze, providing evidence of strong underrepresentation of fir in the pollen deposition. Application of these percentage thresholds to the Słone and Bezedna pollen diagrams indicates that occurrence of fir in the region is possible from 3.5 ky cal BP onwards, though the evidence is not decisive. In the Šumava, a low representation of fir pollen (1-2%) reflecting presence of scattered fir trees was detected as early as ca. 7.0 ky cal BP.
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http://dx.doi.org/10.1016/j.revpalbo.2013.03.006 | DOI Listing |
J Chem Phys
January 2025
Department of Chemistry, New York University, New York, New York 10003, USA.
The water trimer, as the smallest water cluster in which the three-body interactions can manifest, is arguably the most important hydrogen-bonded trimer. Accurate, fully coupled quantum treatment of its excited intermolecular vibrations has long been an elusive goal. Here, we present the methodology that for the first time allows rigorous twelve-dimensional (12D) quantum calculation of the intermolecular vibration-tunneling eigenstates of the water trimer, with the monomers treated as rigid.
View Article and Find Full Text PDFMater Horiz
January 2025
Center for Future Optoelectronic Functional Materials, School of Computer and Electronic Information/School of Artificial Intelligence, Nanjing Normal University, Nanjing 210023, P. R. China.
Given that optical thermometers are widely used due to their unique advantages, this study aims to address critical challenges in existing technologies, such as insufficient sensitivity, limited temperature measurement ranges, and poor signal recognition capabilities. Herein, we develop a thermometer based on the fluorescence intensity ratio (FIR) of Sb-doped CsNaInCl (CsNaInCl:Sb). As the temperature increases from 203 to 323 K, the thermally induced transition from triplet to singlet self-trapped excitons (STEs) leads to enhanced 455 nm photoluminescence (PL) from singlet STE recombination.
View Article and Find Full Text PDFNeural Netw
January 2025
Department of Data Science and Artificial Intelligence, The Hong Kong Polytechnic University, Hong Kong Special Administrative Region; Department of Computing, The Hong Kong Polytechnic University, Hong Kong Special Administrative Region. Electronic address:
In this work, we propose a Fine-grained Hemispheric Asymmetry Network (FG-HANet), an end-to-end deep learning model that leverages hemispheric asymmetry features within 2-Hz narrow frequency bands for accurate and interpretable emotion classification over raw EEG data. In particular, the FG-HANet extracts features not only from original inputs but also from their mirrored versions, and applies Finite Impulse Response (FIR) filters at a granularity as fine as 2-Hz to acquire fine-grained spectral information. Furthermore, to guarantee sufficient attention to hemispheric asymmetry features, we tailor a three-stage training pipeline for the FG-HANet to further boost its performance.
View Article and Find Full Text PDFPlants (Basel)
January 2025
College of Forestry, Fujian Agriculture and Forestry University, Fuzhou 350002, China.
As sustainable forest management gains increasing attention, comprehending the impact of stand density on soil properties and microbial communities is crucial for optimizing forest ecosystem functions. This study employed high-throughput sequencing in conjunction with soil physicochemical analysis to assess the effects of stand density on soil physicochemical properties and microbial community characteristics in Chinese fir plantations, aiming to elucidate the influence of density regulation on ecosystem services. Our results suggested that changes in soil physicochemical properties and microenvironmental conditions were key drivers of soil microbial diversity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
College of Science, China University of Petroleum, Beijing 102249 China; Beijing Key Lab of Oil & Gas Optical Detection Technology, China University of Petroleum, Beijing 102249 China; State Key Lab Heavy Oil Processing, China University of Petroleum, Beijing 102249 China. Electronic address:
Non-contact temperature sensors have gained immense popularity due to their inherent benefits, including the absence of physical interaction with targets and rapid response characteristics. In this work, KBaY(MoO):Pr was successfully synthesized utilizing a high-temperature solid-phase method. Experimental studies have indicated that multi-phonon relaxation (MPR), cross-relaxation (CR), and the unique intervalence charge transfer state (IVCT) exhibited by Pr-Mo contribute to the changes in luminescence properties.
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