During solar salt production, large quantities of bittern, a liquid by-product containing high inorganic substance concentrations, are produced. The purpose of this research was to examine the utilization of waste bittern generated from salterns as a source for Mg production and as an absorbent for carbon dioxide (CO) capture. The study was conducted in a sequential two-step process. At NaOH/Mg molar ratios of 2.70-2.75 and pH 9.5-10.0, > 99% Mg precipitation from the bittern was achieved. After washing with water, 100-120 g/L of precipitate containing 94% Mg(OH) was recovered from the bittern. At the optimum NHOH concentration of 5%, 120 g of sodium bicarbonate precipitate per liter of bittern were recovered, which was equivalent to 63 g CO captured per liter of bittern. These results can be used to support the use of bittern as a resource and reduce economic losses during solar salt production.
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http://dx.doi.org/10.1007/s11356-017-9913-5 | DOI Listing |
Environ Sci Technol
January 2025
State Key Laboratory of Marine Resources Utilization in South China Sea, School of Marine Science and Engineering, Hainan University, Haikou 570228, China.
In response to the 2023 "Action Plan for Methane Emission Control" in China, which mandates precise methane (CH) emission accounting, we developed a dynamic model to estimate CH emissions from fossil-fuel and food systems in China for the period 1990-2020. We also analyzed their socioeconomic drivers through the Logarithmic Mean Divisia Index (LMDI) model. Our analysis revealed an accelerated emission increase (850.
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January 2025
Department of Chemistry, Faculty of Science, University of Maragheh P.O Box 55181-83111 Maragheh Iran.
In this study, we present the design, synthesis, and utilization of a covalent triazine framework (CTF) formed by the condensation of , , -tris(4-(aminomethyl)benzyl)-1,3,5-triazine-2,4,6-triamine and 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine on which silica is immobilized (TPT-TAT/silica) as an innovative catalyst for porphyrins synthesis. Under solvothermal conditions, the condensation of triamine and trialdehyde precursors led to the formation of a covalent triazine framework (CTF) with a high nitrogen content. The resulting CTF is characterized by its extensive porosity and elevated nitrogen levels, which are critical for the creation of catalytic active sites.
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January 2025
Department of Chemistry, Institute of Technical Education and Research, Siksha 'O' Anusandhan Deemed to Be University Bhubaneswar-751030 Odisha India
The widespread use of neodymium-iron-boron (NdFeB) magnets has raised concerns about the environmental impact of their disposal, prompting the need for sustainable recycling strategies. Traditional solvents used in recycling are toxic and flammable, making them risky to use. Ionic liquids are safer and greener options with low vapor pressure, high stability, and less flammability.
View Article and Find Full Text PDFChemistry
January 2025
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, 119991, Moscow, RUSSIAN FEDERATION.
Palladium catalysts form a cornerstone of modern chemistry with upmost scientific and industrial impact. Bulk palladium metal itself is chemically inert, and a sequence of chemical transformations has to be utilized to convert the metal into Pd pre-catalyst covered by ligands. However, the "cocktail" of catalysis concept discovered recently has shown that Pd systems can efficiently operate in catalysis without the necessity of a complicated and expensive pre-installed ligand environment.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute for Carbon Neutralization Technology, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang, 325035, China.
Closed-loop transformation of raw materials into high-value-added products is highly desired for the sustainable development of the society but is seldom achieved. Here, a low-cost, solvent-free and "zero-waste" mechanochemical protocol is reported for the large-scale preparation of cathode materials for sodium-ion batteries (SIBs). This process ensures full utilization of raw materials, effectively reduces water consumption, and simplifies the operating process.
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