Palladium(II)-Catalyzed Deacylative Allylic C-H Alkylation. | LitMetric

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Palladium(II)-Catalyzed Deacylative Allylic C-H Alkylation. | LitMetric

Palladium(II)-Catalyzed Deacylative Allylic C-H Alkylation.

Xiao-Le Zhou Lei Ren Pu-Sheng Wang

J Org Chem

Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China.

Published: September 2017

The first deacylative allylic C-H alkylation has been established by employing the palladium-catalyzed allylic C-H activation and decarboxylative nucleophile generation. A wide scope of nucleophiles are tolerated and densely functionalized alkylation products turn out to be furnished in moderate to good yield. More importantly, this strategy provides an alternative method for the allylic C-H alkylation with less stabilized carbon nucleophiles, and can be further expanded to the synthesis of unconjugated enynes.

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http://dx.doi.org/10.1021/acs.joc.7b00919	DOI Listing

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