Effect of Core-Shell Ceria/Poly(vinylpyrrolidone) (PVP) Nanoparticles Incorporated in Polymer Films and Their Optical Properties.

We fabricated hybrid films of pentaerythritol triacrylate (PETA) with core-shell ceria/poly(vinylpyrrolidone) (PVP) nanoparticles, which consist of cerium oxide as the core and PVP as the shell, and investigated the film optical properties. In this study, we used ceria/PVP nanoparticles with average diameters of 37, 49 and 91 nm. We obtained translucent films consisting of PETA with core-shell ceria/PVP nanoparticles. The core-shell ceria/PVP nanoparticles can reduce the transmittance of near-ultraviolet light. The transmittance of visible light and haze values depends not only on the thickness of the films, but also on the average diameter of the nanoparticles. A SEM observation and the optical analyses prove that the core-shell ceria/PVP nanoparticles do not aggregate into the PETA matrix.